Inorganic Chemistry, volume 42, issue 15, pages 4498-4500
The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate
Publication type: Journal Article
Publication date: 2003-06-20
Journal:
Inorganic Chemistry
Q1
Q1
SJR: 0.928
CiteScore: 7.6
Impact factor: 4.3
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The copolymerization of 2-(3,4-epoxycyclohexyl)ethyl-trimethoxysilane and carbon dioxide catalyzed by (salen)Cr(III)Cl (H(2)salen = N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylenediimine) with 2.5 equiv of N-MeIm as cocatalyst affords a polycarbonate devoid of polyether linkages, along with only a trace quantity of cyclic carbonate. The presence of the trimethoxysilane functionality in the epoxide not only provided the reactant monomer and product copolymer high solubility in liquid carbon dioxide but also provided the ability to cross-link the copolymer and thereby greatly alter the physical properties of the thus formed polycarbonate. In addition, the enhanced solubility of the copolymer in liquid CO(2) furnishes a ready means of removing the highly colored metal catalyst from the polycarbonate product.
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Darensbourg D. J., Rodgers J. L., Fang C. C. The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate // Inorganic Chemistry. 2003. Vol. 42. No. 15. pp. 4498-4500.
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Darensbourg D. J., Rodgers J. L., Fang C. C. The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate // Inorganic Chemistry. 2003. Vol. 42. No. 15. pp. 4498-4500.
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TY - JOUR
DO - 10.1021/ic034363m
UR - https://doi.org/10.1021/ic034363m
TI - The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate
T2 - Inorganic Chemistry
AU - Darensbourg, Donald J.
AU - Rodgers, Jody L.
AU - Fang, Cindy C
PY - 2003
DA - 2003/06/20
PB - American Chemical Society (ACS)
SP - 4498-4500
IS - 15
VL - 42
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2003_Darensbourg,
author = {Donald J. Darensbourg and Jody L. Rodgers and Cindy C Fang},
title = {The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate},
journal = {Inorganic Chemistry},
year = {2003},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ic034363m},
number = {15},
pages = {4498--4500},
doi = {10.1021/ic034363m}
}
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Darensbourg, Donald J., et al. “The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate.” Inorganic Chemistry, vol. 42, no. 15, Jun. 2003, pp. 4498-4500. https://doi.org/10.1021/ic034363m.