Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
O. Kazheva
1
,
Grigorii G Alexandrov
2
,
A. Kravchenko
3
,
I. Kosenko
4
,
Irina A Lobanova
4
,
Igor B. Sivaev
4
,
Oleg A. Filippov
4
,
Elena S. Shubina
4
,
V. Bregadze
4
,
V. Starodub
3, 5
,
Lev V Titov
1
,
L. Buravov
1
,
Oleg A. Dyachenko
1
3
V. N. Karazin Kharkiv National University, Svoboda Sq. 4, 61077 Kharkiv, Ukraine
|
Publication type: Journal Article
Publication date: 2010-12-15
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
21158466
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Molecular conductors based on the 8-hydroxy cobalt bis(dicarbollide) anion, (TMTTF)[8-HO-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (1), (BMDT-TTF)[8-HO-3,3'-Co(1,2-C2B9H10) (1',2'-C2B9H11)] (2), and (BEDT-TTF)[8-HO-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)] (3), were synthesized, and their crystal structures and electrical conductivities were determined. Compounds 2 and 3 are isostructural to the corresponding radical-cation salts of the parent cobalt bis(dicarbollide). All of the radical-cation salts prepared were found to be semiconductors. The relative stability of the rotation conformers of the [8-HO-3,3'-Co(1,2-C2B9H10)(1',2'-C2B9H11)](-) anion was estimated using DFT/BP86 quantum chemical calculations.
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Citations from 2024:
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Kazheva O. et al. Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion // Inorganic Chemistry. 2010. Vol. 50. No. 2. pp. 444-450.
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Kazheva O., Alexandrov G. G., Kravchenko A., Kosenko I., Lobanova I. A., Sivaev I. B., Filippov O. A., Shubina E. S., Bregadze V., Starodub V., Titov L. V., Buravov L., Dyachenko O. A. Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion // Inorganic Chemistry. 2010. Vol. 50. No. 2. pp. 444-450.
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RIS
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TY - JOUR
DO - 10.1021/ic101168b
UR - https://doi.org/10.1021/ic101168b
TI - Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion
T2 - Inorganic Chemistry
AU - Kazheva, O.
AU - Alexandrov, Grigorii G
AU - Kravchenko, A.
AU - Kosenko, I.
AU - Lobanova, Irina A
AU - Sivaev, Igor B.
AU - Filippov, Oleg A.
AU - Shubina, Elena S.
AU - Bregadze, V.
AU - Starodub, V.
AU - Titov, Lev V
AU - Buravov, L.
AU - Dyachenko, Oleg A.
PY - 2010
DA - 2010/12/15
PB - American Chemical Society (ACS)
SP - 444-450
IS - 2
VL - 50
PMID - 21158466
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2010_Kazheva,
author = {O. Kazheva and Grigorii G Alexandrov and A. Kravchenko and I. Kosenko and Irina A Lobanova and Igor B. Sivaev and Oleg A. Filippov and Elena S. Shubina and V. Bregadze and V. Starodub and Lev V Titov and L. Buravov and Oleg A. Dyachenko},
title = {Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion},
journal = {Inorganic Chemistry},
year = {2010},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ic101168b},
number = {2},
pages = {444--450},
doi = {10.1021/ic101168b}
}
Cite this
MLA
Copy
Kazheva, O., et al. “Molecular Conductors with a 8-Hydroxy cobalt Bis(dicarbollide) Anion.” Inorganic Chemistry, vol. 50, no. 2, Dec. 2010, pp. 444-450. https://doi.org/10.1021/ic101168b.