Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals
1
Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, TU Lisbon, Av. Rovisco Pais, 1049-001 Lisbon, Portugal
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Тип публикации: Journal Article
Дата публикации: 2011-04-01
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
21456552
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A radical mechanism of hydrocarbon oxidations with the environmentally friendly and cheap homogeneous nontransition metal system [Al(H(2)O)(6)](3+)/H(2)O(2)/MeCN-H(2)O was proposed for the first time on the basis of DFT calculations. A dramatic activation of H(2)O(2) toward homolysis in the key intermediate [Al(H(2)O)(4)(OOH)(H(2)O(2))](2+) due to the presence of the easily oxidizable OOH coligand provides, without a change of metal oxidation state, the generation of HO(•) radicals, which then oxidize hydrocarbons. Nonradical mechanisms of the olefin epoxidation with the same catalytic system were also investigated.
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Kuznetsov M. et al. Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals // Inorganic Chemistry. 2011. Vol. 50. No. 9. pp. 3996-4005.
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Kuznetsov M., Kozlov Y. N., Mandelli D., Pombeiro A. J. L., Shul'pin G. B. Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals // Inorganic Chemistry. 2011. Vol. 50. No. 9. pp. 3996-4005.
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TY - JOUR
DO - 10.1021/ic102476x
UR - https://doi.org/10.1021/ic102476x
TI - Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals
T2 - Inorganic Chemistry
AU - Kuznetsov, Maxim
AU - Kozlov, Yuriy N.
AU - Mandelli, Dalmo
AU - Pombeiro, Armando J. L.
AU - Shul'pin, Georgiy B.
PY - 2011
DA - 2011/04/01
PB - American Chemical Society (ACS)
SP - 3996-4005
IS - 9
VL - 50
PMID - 21456552
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2011_Kuznetsov,
author = {Maxim Kuznetsov and Yuriy N. Kozlov and Dalmo Mandelli and Armando J. L. Pombeiro and Georgiy B. Shul'pin},
title = {Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals},
journal = {Inorganic Chemistry},
year = {2011},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ic102476x},
number = {9},
pages = {3996--4005},
doi = {10.1021/ic102476x}
}
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MLA
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Kuznetsov, Maxim, et al. “Mechanism of Al3+-Catalyzed Oxidations of Hydrocarbons: Dramatic Activation of H2O2 toward O−O Homolysis in Complex [Al(H2O)4(OOH)(H2O2)]2+ Explains the Formation of HO• Radicals.” Inorganic Chemistry, vol. 50, no. 9, Apr. 2011, pp. 3996-4005. https://doi.org/10.1021/ic102476x.