Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies
Lina M. epstein
1
,
Elena S. Shubina
1
,
Ekaterina V Bakhmutova
1
,
Liliya N Saitkulova
1
,
Vladimir I Bakhmutov
1
,
Anatolii L Chistyakov
1
,
Ivan V Stankevich
1
Publication type: Journal Article
Publication date: 1998-05-15
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The interaction of different proton donors with ionic (Bu4NBH4) and neutral (BH3NEt3, BH3P(OEt)3) boron hydrides was studied by IR and NMR spectroscopy in solution (CH2Cl2, C6H14, and C6D12). A close similarity was observed between the spectral and thermodynamic properties of these unusual BH···HX and those of classical H bonds. The typical characteristics of hydrogen bonding, such as linearity of the fragment H···HX, lengthening of X−H and H−B bonds, and strong electron redistribution, were confirmed by ab initio calculations.
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GOST
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epstein L. M. et al. Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies // Inorganic Chemistry. 1998. Vol. 37. No. 12. pp. 3013-3017.
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epstein L. M., Shubina E. S., Bakhmutova E. V., Saitkulova L. N., Bakhmutov V. I., Chistyakov A. L., Stankevich I. V. Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies // Inorganic Chemistry. 1998. Vol. 37. No. 12. pp. 3013-3017.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ic971461x
UR - https://doi.org/10.1021/ic971461x
TI - Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies
T2 - Inorganic Chemistry
AU - epstein, Lina M.
AU - Shubina, Elena S.
AU - Bakhmutova, Ekaterina V
AU - Saitkulova, Liliya N
AU - Bakhmutov, Vladimir I
AU - Chistyakov, Anatolii L
AU - Stankevich, Ivan V
PY - 1998
DA - 1998/05/15
PB - American Chemical Society (ACS)
SP - 3013-3017
IS - 12
VL - 37
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_epstein,
author = {Lina M. epstein and Elena S. Shubina and Ekaterina V Bakhmutova and Liliya N Saitkulova and Vladimir I Bakhmutov and Anatolii L Chistyakov and Ivan V Stankevich},
title = {Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies},
journal = {Inorganic Chemistry},
year = {1998},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ic971461x},
number = {12},
pages = {3013--3017},
doi = {10.1021/ic971461x}
}
Cite this
MLA
Copy
epstein, Lina M., et al. “Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies.” Inorganic Chemistry, vol. 37, no. 12, May. 1998, pp. 3013-3017. https://doi.org/10.1021/ic971461x.
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