[Fe(PMA)]n+ (n = 1,2): good models of iron-bleomycins and examples of mononuclear non-heme iron complexes with significant oxygen-activation capabilities
Тип публикации: Journal Article
Дата публикации: 1993-09-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The Fe(II) and Fe(III) complexes of a designed ligand PMAH that mimics the metal-binding portion of the antitumor drug bleomycin (BLM) have been isolated and characterized by spectroscopic techniques. In both [Fe II (PMA)]Cl.MeOH (4) and [Fe III (PMA)] (NO 3 ) 2 -DMSO (5), the deprotonated PMA - framework is ligated to the metal center through five nitrogens located in the primary and secondary amines, pyrimidine and imidazole rings, and the amide moiety. The sixth coordination site on iron in these complexes is occupied by a solvent molecule that is easily replaceable. Similarities in spectral and chemical behaviors of these two model complexes with those of the Fe(II) and Fe(III) complexes of BLM strongly suggest that the drug employs the same set of donor centers to bind iron
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143
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ГОСТ
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Guajardo R. J. et al. [Fe(PMA)]n+ (n = 1,2): good models of iron-bleomycins and examples of mononuclear non-heme iron complexes with significant oxygen-activation capabilities // Journal of the American Chemical Society. 1993. Vol. 115. No. 18. pp. 7971-7977.
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Guajardo R. J., Hudson S. E., Brown S. J., Mascharak P. K. [Fe(PMA)]n+ (n = 1,2): good models of iron-bleomycins and examples of mononuclear non-heme iron complexes with significant oxygen-activation capabilities // Journal of the American Chemical Society. 1993. Vol. 115. No. 18. pp. 7971-7977.
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TY - JOUR
DO - 10.1021/ja00071a006
UR - https://doi.org/10.1021/ja00071a006
TI - [Fe(PMA)]n+ (n = 1,2): good models of iron-bleomycins and examples of mononuclear non-heme iron complexes with significant oxygen-activation capabilities
T2 - Journal of the American Chemical Society
AU - Guajardo, Richard J
AU - Hudson, Samuel E
AU - Brown, Steven J
AU - Mascharak, Pradip K
PY - 1993
DA - 1993/09/01
PB - American Chemical Society (ACS)
SP - 7971-7977
IS - 18
VL - 115
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{1993_Guajardo,
author = {Richard J Guajardo and Samuel E Hudson and Steven J Brown and Pradip K Mascharak},
title = {[Fe(PMA)]n+ (n = 1,2): good models of iron-bleomycins and examples of mononuclear non-heme iron complexes with significant oxygen-activation capabilities},
journal = {Journal of the American Chemical Society},
year = {1993},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja00071a006},
number = {18},
pages = {7971--7977},
doi = {10.1021/ja00071a006}
}
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MLA
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Guajardo, Richard J., et al. “[Fe(PMA)]n+ (n = 1,2): good models of iron-bleomycins and examples of mononuclear non-heme iron complexes with significant oxygen-activation capabilities.” Journal of the American Chemical Society, vol. 115, no. 18, Sep. 1993, pp. 7971-7977. https://doi.org/10.1021/ja00071a006.
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