Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites
Publication type: Journal Article
Publication date: 1993-09-01
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A simple route to the production of high-quality CdE (E=S, Se, Te) semiconductor nanocrystallites is presented. Crystallites from ∼12 A to ∼115 A in diameter with consistent crystal structure, surface derivatization, and a high degree of monodispersity are prepared in a single reaction. The synthesis is based on the pyrolysis of organometallic reagents by injection into a hot coordinating solvent. This provides temporally discrete nucleation and permits controlled growth of macroscopic quantities of nanocrystallites. Size selective precipitation of crystallites from Portions of the growth solution isolates samples with narrow size distributions (<5% rms in diameter). High sample quality results in sharp absorption features and strong «band-edge» emission which is tunable with particle size and choice of material
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Murray C. B., Norris D. J., Bawendi M. G. Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites // Journal of the American Chemical Society. 1993. Vol. 115. No. 19. pp. 8706-8715.
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Murray C. B., Norris D. J., Bawendi M. G. Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites // Journal of the American Chemical Society. 1993. Vol. 115. No. 19. pp. 8706-8715.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja00072a025
UR - https://doi.org/10.1021/ja00072a025
TI - Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites
T2 - Journal of the American Chemical Society
AU - Murray, Christopher B
AU - Norris, David J
AU - Bawendi, Moungi G.
PY - 1993
DA - 1993/09/01
PB - American Chemical Society (ACS)
SP - 8706-8715
IS - 19
VL - 115
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{1993_Murray,
author = {Christopher B Murray and David J Norris and Moungi G. Bawendi},
title = {Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites},
journal = {Journal of the American Chemical Society},
year = {1993},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja00072a025},
number = {19},
pages = {8706--8715},
doi = {10.1021/ja00072a025}
}
Cite this
MLA
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Murray, Christopher B., et al. “Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites.” Journal of the American Chemical Society, vol. 115, no. 19, Sep. 1993, pp. 8706-8715. https://doi.org/10.1021/ja00072a025.