Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases.
Evgenii I Gutsul
1
,
Oleg A. Filippov
1
,
Vladislava A Levina
1
,
Dmitriy A Valyaev
1
,
Lina M. epstein
1
,
Agustí Lledós
1
,
Publication type: Journal Article
Publication date: 2006-02-25
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
16536499
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The interaction of CpM(CO)3H (M = Mo, W) hydrides as proton donors with different bases (B = pyridine, (n-Oc)3PO, ((CH3)2N)3PO, H3BNEt3) was studied by variable temperature IR spectroscopy and theoretically by DFT/B3LYP calculations. The data obtained show for the first time the formation of intermolecular hydrogen bonds between the neutral transition metal hydrides and bases in solutions of low polarity. These M-H...B hydrogen bonds are shown to precede the hydrides' deprotonation.
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23
Total citations:
23
Citations from 2024:
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(8.7%)
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GOST
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belkova N. V. et al. Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases. // Journal of the American Chemical Society. 2006. Vol. 128. No. 11. pp. 3486-3487.
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belkova N. V., Gutsul E. I., Filippov O. A., Levina V. A., Valyaev D. A., epstein L. M., Lledós A., Shubina E. S. Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases. // Journal of the American Chemical Society. 2006. Vol. 128. No. 11. pp. 3486-3487.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja057867n
UR - https://doi.org/10.1021/ja057867n
TI - Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases.
T2 - Journal of the American Chemical Society
AU - belkova, Natalia V.
AU - Gutsul, Evgenii I
AU - Filippov, Oleg A.
AU - Levina, Vladislava A
AU - Valyaev, Dmitriy A
AU - epstein, Lina M.
AU - Lledós, Agustí
AU - Shubina, Elena S.
PY - 2006
DA - 2006/02/25
PB - American Chemical Society (ACS)
SP - 3486-3487
IS - 11
VL - 128
PMID - 16536499
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2006_belkova,
author = {Natalia V. belkova and Evgenii I Gutsul and Oleg A. Filippov and Vladislava A Levina and Dmitriy A Valyaev and Lina M. epstein and Agustí Lledós and Elena S. Shubina},
title = {Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases.},
journal = {Journal of the American Chemical Society},
year = {2006},
volume = {128},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ja057867n},
number = {11},
pages = {3486--3487},
doi = {10.1021/ja057867n}
}
Cite this
MLA
Copy
belkova, Natalia V., et al. “Intermolecular hydrogen bonding between neutral transition metal hydrides (eta(5)-C5H5)M(CO)3H (M = Mo, W) and bases..” Journal of the American Chemical Society, vol. 128, no. 11, Feb. 2006, pp. 3486-3487. https://doi.org/10.1021/ja057867n.
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