Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen
Тип публикации: Journal Article
Дата публикации: 2007-03-28
scimago Q1
Tоп 10% SciMago
wos Q1
white level БС1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
17388595
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Electron-rich dialkylbiaryl phosphines, which comprise a common class of supporting ligands for Pd-catalyzed cross-coupling reactions, are highly resistant toward oxidation by molecular oxygen. Presented herein are possible reasons why this class of phosphine ligands manifests this property. Experimental and theoretical data suggest that the two alkyl substituents on the phosphorus center and the 2' and 6' positions of the biaryl backbone play an important role in inhibiting oxidation of this class of ligands.
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162
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162
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ГОСТ
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Barder T. E., Buchwald S. L. Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen // Journal of the American Chemical Society. 2007. Vol. 129. No. 16. pp. 5096-5101.
ГОСТ со всеми авторами (до 50)
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Barder T. E., Buchwald S. L. Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen // Journal of the American Chemical Society. 2007. Vol. 129. No. 16. pp. 5096-5101.
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TY - JOUR
DO - 10.1021/ja0683180
UR - https://doi.org/10.1021/ja0683180
TI - Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen
T2 - Journal of the American Chemical Society
AU - Barder, Timothy E
AU - Buchwald, Stephen L.
PY - 2007
DA - 2007/03/28
PB - American Chemical Society (ACS)
SP - 5096-5101
IS - 16
VL - 129
PMID - 17388595
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2007_Barder,
author = {Timothy E Barder and Stephen L. Buchwald},
title = {Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen},
journal = {Journal of the American Chemical Society},
year = {2007},
volume = {129},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja0683180},
number = {16},
pages = {5096--5101},
doi = {10.1021/ja0683180}
}
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MLA
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Barder, Timothy E., and Stephen L. Buchwald. “Rationale Behind the Resistance of Dialkylbiaryl Phosphines toward Oxidation by Molecular Oxygen.” Journal of the American Chemical Society, vol. 129, no. 16, Mar. 2007, pp. 5096-5101. https://doi.org/10.1021/ja0683180.
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