Journal of the American Chemical Society, volume 135, issue 18, pages 7073-7079
The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis
César A. Urbina-Blanco
1
,
Albert Poater
2
,
T. Lébl
1
,
Simone Manzini
1
,
Luigi Maria Cavallo
3, 4
,
2
Institut de Química Computacional
i Catàlisi, Departament de Química, University of Girona, Campus de Montilivi sn, 17071 Girona, Catalonia,
Spain
|
Publication type: Journal Article
Publication date: 2013-04-25
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Olefin metathesis is a powerful tool for the formation of carbon-carbon double bonds. Several families of well-defined ruthenium (Ru) catalysts have been developed during the past 20 years; however, the reaction mechanism for all such complexes was assumed to be the same. In the present study, the initiation mechanism of Ru-indenylidene complexes was examined and compared with that of benzylidene counterparts. It was discovered that not all indenylidene complexes followed the same mechanism, highlighting the importance of steric and electronic properties of so-called spectator ligands, and that there is no single mechanism for the Ru-based olefin metathesis reaction. The experimental findings are supported quantitatively by DFT calculations.
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Citations by publishers
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5
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15
20
25
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1 publication, 1.05%
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5
10
15
20
25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Urbina-Blanco C. A. et al. The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 7073-7079.
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Urbina-Blanco C. A., Poater A., Lébl T., Manzini S., Slawin A. M. Z., Cavallo L. M., Nolan S. P. The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 7073-7079.
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TY - JOUR
DO - 10.1021/ja402700p
UR - https://doi.org/10.1021/ja402700p
TI - The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis
T2 - Journal of the American Chemical Society
AU - Manzini, Simone
AU - Urbina-Blanco, César A.
AU - Poater, Albert
AU - Lébl, T.
AU - Slawin, Alexandra M. Z.
AU - Cavallo, Luigi Maria
AU - Nolan, Steven P.
PY - 2013
DA - 2013/04/25 00:00:00
PB - American Chemical Society (ACS)
SP - 7073-7079
IS - 18
VL - 135
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2013_Urbina-Blanco,
author = {Simone Manzini and César A. Urbina-Blanco and Albert Poater and T. Lébl and Alexandra M. Z. Slawin and Luigi Maria Cavallo and Steven P. Nolan},
title = {The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ja402700p},
number = {18},
pages = {7073--7079},
doi = {10.1021/ja402700p}
}
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MLA
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Urbina-Blanco, César A., et al. “The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis.” Journal of the American Chemical Society, vol. 135, no. 18, Apr. 2013, pp. 7073-7079. https://doi.org/10.1021/ja402700p.