том 135 издание 18 страницы 7073-7079

The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis

Тип публикацииJournal Article
Дата публикации2013-04-25
scimago Q1
wos Q1
БС1
SJR5.554
CiteScore22.5
Impact factor15.6
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Olefin metathesis is a powerful tool for the formation of carbon-carbon double bonds. Several families of well-defined ruthenium (Ru) catalysts have been developed during the past 20 years; however, the reaction mechanism for all such complexes was assumed to be the same. In the present study, the initiation mechanism of Ru-indenylidene complexes was examined and compared with that of benzylidene counterparts. It was discovered that not all indenylidene complexes followed the same mechanism, highlighting the importance of steric and electronic properties of so-called spectator ligands, and that there is no single mechanism for the Ru-based olefin metathesis reaction. The experimental findings are supported quantitatively by DFT calculations.
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Urbina-Blanco C. A. et al. The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 7073-7079.
ГОСТ со всеми авторами (до 50) Скопировать
Urbina-Blanco C. A., Poater A., Lébl T., Manzini S., Slawin A. M. Z., Cavallo L. M., Nolan S. P. The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 7073-7079.
RIS |
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TY - JOUR
DO - 10.1021/ja402700p
UR - https://doi.org/10.1021/ja402700p
TI - The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis
T2 - Journal of the American Chemical Society
AU - Urbina-Blanco, César A.
AU - Poater, Albert
AU - Lébl, T.
AU - Manzini, Simone
AU - Slawin, Alexandra M. Z.
AU - Cavallo, Luigi Maria
AU - Nolan, Steven P.
PY - 2013
DA - 2013/04/25
PB - American Chemical Society (ACS)
SP - 7073-7079
IS - 18
VL - 135
PMID - 23617632
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2013_Urbina-Blanco,
author = {César A. Urbina-Blanco and Albert Poater and T. Lébl and Simone Manzini and Alexandra M. Z. Slawin and Luigi Maria Cavallo and Steven P. Nolan},
title = {The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ja402700p},
number = {18},
pages = {7073--7079},
doi = {10.1021/ja402700p}
}
MLA
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Urbina-Blanco, César A., et al. “The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis.” Journal of the American Chemical Society, vol. 135, no. 18, Apr. 2013, pp. 7073-7079. https://doi.org/10.1021/ja402700p.