Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes
Publication type: Journal Article
Publication date: 2009-08-05
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
19705909
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A general rhodium-catalyzed oxidative coupling reaction between internal alkynes and aryl aldimines is described. This process affords 3,4-disubstituted isoquinolines in good yield and high regioselectivity. Preliminary mechanistic studies suggest that the C-N bond formation arises from the reductive elimination of a rhodium(III) species.
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Metrics
449
Total citations:
449
Citations from 2025:
5
(1.11%)
Cite this
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MLA
Cite this
GOST
Copy
Guimond N., Fagnou K. Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes // Journal of the American Chemical Society. 2009. Vol. 131. No. 34. pp. 12050-12051.
GOST all authors (up to 50)
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Guimond N., Fagnou K. Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes // Journal of the American Chemical Society. 2009. Vol. 131. No. 34. pp. 12050-12051.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja904380q
UR - https://doi.org/10.1021/ja904380q
TI - Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes
T2 - Journal of the American Chemical Society
AU - Guimond, Nicolas
AU - Fagnou, Keith
PY - 2009
DA - 2009/08/05
PB - American Chemical Society (ACS)
SP - 12050-12051
IS - 34
VL - 131
PMID - 19705909
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Guimond,
author = {Nicolas Guimond and Keith Fagnou},
title = {Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes},
journal = {Journal of the American Chemical Society},
year = {2009},
volume = {131},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ja904380q},
number = {34},
pages = {12050--12051},
doi = {10.1021/ja904380q}
}
Cite this
MLA
Copy
Guimond, Nicolas, and Keith Fagnou. “Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes.” Journal of the American Chemical Society, vol. 131, no. 34, Aug. 2009, pp. 12050-12051. https://doi.org/10.1021/ja904380q.