A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior
1
3
Vernadskii
Institute of General and Inorganic Chemistry, The National Academy of Sciences of Ukraine, Kyiv 03680, Ukraine
|
Publication type: Journal Article
Publication date: 2015-07-28
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
26199996
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual geometry as a source of magnetically anisotropic ground state. Here we report a cobalt(II) cage complex with a trigonal prism geometry showing single ion magnet behavior with very high Orbach relaxation barrier of 152 cm(-1). This, to our knowledge, is the largest reported relaxation barrier for a cobalt-based mononuclear SMM. The trigonal prismatic coordination provided by the macrocyclic ligand gives intrinsically more stable molecular species than previously reported SMMs, thus making this type of cage complexes more amendable to possible functionalization that will boost their magnetic anisotropy even further.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
10
20
30
40
50
60
|
|
|
Inorganic Chemistry
55 publications, 17.19%
|
|
|
Dalton Transactions
55 publications, 17.19%
|
|
|
New Journal of Chemistry
13 publications, 4.06%
|
|
|
European Journal of Inorganic Chemistry
12 publications, 3.75%
|
|
|
Chemistry - A European Journal
11 publications, 3.44%
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
9 publications, 2.81%
|
|
|
Chemical Communications
9 publications, 2.81%
|
|
|
Magnetochemistry
9 publications, 2.81%
|
|
|
Chemical Science
9 publications, 2.81%
|
|
|
Inorganic Chemistry Frontiers
9 publications, 2.81%
|
|
|
Journal of the American Chemical Society
6 publications, 1.88%
|
|
|
ChemistrySelect
5 publications, 1.56%
|
|
|
Physical Chemistry Chemical Physics
5 publications, 1.56%
|
|
|
Molecules
5 publications, 1.56%
|
|
|
Angewandte Chemie
5 publications, 1.56%
|
|
|
Angewandte Chemie - International Edition
5 publications, 1.56%
|
|
|
RSC Advances
4 publications, 1.25%
|
|
|
ACS Omega
4 publications, 1.25%
|
|
|
Polyhedron
4 publications, 1.25%
|
|
|
Journal of Molecular Structure
4 publications, 1.25%
|
|
|
Inorganica Chimica Acta
3 publications, 0.94%
|
|
|
Journal of Materials Chemistry C
3 publications, 0.94%
|
|
|
Russian Chemical Bulletin
3 publications, 0.94%
|
|
|
Crystal Growth and Design
3 publications, 0.94%
|
|
|
Physical Review B
3 publications, 0.94%
|
|
|
Inorganics
3 publications, 0.94%
|
|
|
Coordination Chemistry Reviews
3 publications, 0.94%
|
|
|
Journal of Magnetism and Magnetic Materials
3 publications, 0.94%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
3 publications, 0.94%
|
|
|
10
20
30
40
50
60
|
Publishers
|
20
40
60
80
100
120
|
|
|
Royal Society of Chemistry (RSC)
110 publications, 34.38%
|
|
|
American Chemical Society (ACS)
74 publications, 23.13%
|
|
|
Wiley
52 publications, 16.25%
|
|
|
Elsevier
27 publications, 8.44%
|
|
|
MDPI
18 publications, 5.63%
|
|
|
Pleiades Publishing
14 publications, 4.38%
|
|
|
Springer Nature
6 publications, 1.88%
|
|
|
American Physical Society (APS)
4 publications, 1.25%
|
|
|
AIP Publishing
3 publications, 0.94%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 0.31%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.31%
|
|
|
International Union of Crystallography (IUCr)
1 publication, 0.31%
|
|
|
World Scientific
1 publication, 0.31%
|
|
|
IOP Publishing
1 publication, 0.31%
|
|
|
Cellule MathDoc/Centre Mersenne
1 publication, 0.31%
|
|
|
Hans Publishers
1 publication, 0.31%
|
|
|
Taylor & Francis
1 publication, 0.31%
|
|
|
The Russian Academy of Sciences
1 publication, 0.31%
|
|
|
Bentham Science Publishers Ltd.
1 publication, 0.31%
|
|
|
20
40
60
80
100
120
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
320
Total citations:
320
Citations from 2024:
43
(13%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Novikov V. V. et al. A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior // Journal of the American Chemical Society. 2015. Vol. 137. No. 31. pp. 9792-9795.
GOST all authors (up to 50)
Copy
Novikov V. V., Pavlov A., Nelyubina Y. V., Boulon M., Varzatskii O. A., Voloshin Y. Z., Winpenny R. E. P. A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior // Journal of the American Chemical Society. 2015. Vol. 137. No. 31. pp. 9792-9795.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.5b05739
UR - https://doi.org/10.1021/jacs.5b05739
TI - A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior
T2 - Journal of the American Chemical Society
AU - Novikov, Valentin V
AU - Pavlov, Alexander
AU - Nelyubina, Yulia V.
AU - Boulon, M.-E.
AU - Varzatskii, Oleg A
AU - Voloshin, Yan Z.
AU - Winpenny, Richard E. P.
PY - 2015
DA - 2015/07/28
PB - American Chemical Society (ACS)
SP - 9792-9795
IS - 31
VL - 137
PMID - 26199996
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Novikov,
author = {Valentin V Novikov and Alexander Pavlov and Yulia V. Nelyubina and M.-E. Boulon and Oleg A Varzatskii and Yan Z. Voloshin and Richard E. P. Winpenny},
title = {A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior},
journal = {Journal of the American Chemical Society},
year = {2015},
volume = {137},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jacs.5b05739},
number = {31},
pages = {9792--9795},
doi = {10.1021/jacs.5b05739}
}
Cite this
MLA
Copy
Novikov, Valentin V., et al. “A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior.” Journal of the American Chemical Society, vol. 137, no. 31, Jul. 2015, pp. 9792-9795. https://doi.org/10.1021/jacs.5b05739.