ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure
Yoshinori Kuno
1
,
Cedric Tassel
1, 2
,
Koji Fujita
1
,
Dmitry Batuk
3
,
Artem M. Abakumov
3, 4
,
Kazuki Shitara
5
,
A. kuwabara
5
,
Hiroki Moriwake
5
,
Daichi Watabe
1
,
Clemens Ritter
6
,
Craig Brown
7
,
Fumitaka Takeiri
1
,
Ryu-ta Abe
1
,
Yoji Kobayashi
1
,
Katsuhisa Tanaka
1
,
Hiroshi KAGEYAMA
1, 8
5
Nanostructures Research Laboratory, Nagoya 456-8587, Japan
|
Publication type: Journal Article
Publication date: 2016-12-02
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
27960353
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
By using a high-pressure reaction, we prepared a new oxynitride ZnTaO2N that crystallizes in a centrosymmetric (R3̅c) high-temperature LiNbO3-type structure (HTLN-type). The stabilization of the HTLN-type structure down to low temperatures (at least 20 K) makes it possible to investigate not only the stability of this phase, but also the phase transition to a noncentrosymmetric (R3c) LiNbO3-type structure (LN-type) which is yet to be clarified. Synchrotron and neutron diffraction studies in combination with transmission electron microscopy show that Zn is located at a disordered 12c site instead of 6a, implying an order-disorder mechanism of the phase transition. It is found that the closed d-shell of Zn2+, as well as the high-valent Ta5+ ion, is responsible for the stabilization of the HTLN-type structure, affording a novel quasitriangular ZnO2N coordination. Interestingly, only 3% Zn substitution for MnTaO2N induces a phase transition from LN- to HTLN-type structure, implying the proximity in energy between the two structural types, which is supported by the first-principles calculations.
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Citations from 2024:
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GOST
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Kuno Y. et al. ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure // Journal of the American Chemical Society. 2016. Vol. 138. No. 49. pp. 15950-15955.
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Kuno Y., Tassel C., Fujita K., Batuk D., Abakumov A. M., Shitara K., kuwabara A., Moriwake H., Watabe D., Ritter C., Brown C., Yamamoto T., Takeiri F., Abe R., Kobayashi Y., Tanaka K., KAGEYAMA H. ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure // Journal of the American Chemical Society. 2016. Vol. 138. No. 49. pp. 15950-15955.
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RIS
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TY - JOUR
DO - 10.1021/jacs.6b08635
UR - https://doi.org/10.1021/jacs.6b08635
TI - ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure
T2 - Journal of the American Chemical Society
AU - Kuno, Yoshinori
AU - Tassel, Cedric
AU - Fujita, Koji
AU - Batuk, Dmitry
AU - Abakumov, Artem M.
AU - Shitara, Kazuki
AU - kuwabara, A.
AU - Moriwake, Hiroki
AU - Watabe, Daichi
AU - Ritter, Clemens
AU - Brown, Craig
AU - Yamamoto, Takafumi
AU - Takeiri, Fumitaka
AU - Abe, Ryu-ta
AU - Kobayashi, Yoji
AU - Tanaka, Katsuhisa
AU - KAGEYAMA, Hiroshi
PY - 2016
DA - 2016/12/02
PB - American Chemical Society (ACS)
SP - 15950-15955
IS - 49
VL - 138
PMID - 27960353
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Kuno,
author = {Yoshinori Kuno and Cedric Tassel and Koji Fujita and Dmitry Batuk and Artem M. Abakumov and Kazuki Shitara and A. kuwabara and Hiroki Moriwake and Daichi Watabe and Clemens Ritter and Craig Brown and Takafumi Yamamoto and Fumitaka Takeiri and Ryu-ta Abe and Yoji Kobayashi and Katsuhisa Tanaka and Hiroshi KAGEYAMA},
title = {ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure},
journal = {Journal of the American Chemical Society},
year = {2016},
volume = {138},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jacs.6b08635},
number = {49},
pages = {15950--15955},
doi = {10.1021/jacs.6b08635}
}
Cite this
MLA
Copy
Kuno, Yoshinori, et al. “ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure.” Journal of the American Chemical Society, vol. 138, no. 49, Dec. 2016, pp. 15950-15955. https://doi.org/10.1021/jacs.6b08635.
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