Carbon states in carbon-encapsulated nickel nanoparticles studied by means of X-ray absorption, emission, and photoelectron spectroscopies
V. R. Galakhov
1, 2
,
A. Buling
3
,
M. Neumann
3
,
N. A. Ovechkina
1
,
A. S. Shkvarin
1
,
A. S. Semenova
4
,
M.A. Uimin
1
,
A.Ye. Yermakov
1
,
E. Z. Kurmaev
1
,
O. Yu. Vilkov
5, 6
,
Publication type: Journal Article
Publication date: 2011-12-01
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
The electronic structure of nickel nanoparticles encapsulated in carbon was characterized by photoelectron, X-ray absorption, and X-ray emission spectroscopies. Experimental spectra were compared with the density of states calculated in the frame of density functional theory. The carbon shell of Ni nanoparticles has been found to be multilayer graphene with a significant (about 6%) amount of Stone–Wales defects. Results of the experiments evidence protection of the metallic nanoparticles from environmental degradation by providing a barrier against oxidation at least for 2 years. Exposure in air for 2 years leads to oxidation only of the carbon shell of Ni@C nanoparticles with coverage of functional groups.
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Total citations:
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Citations from 2024:
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GOST
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Galakhov V. R. et al. Carbon states in carbon-encapsulated nickel nanoparticles studied by means of X-ray absorption, emission, and photoelectron spectroscopies // Journal of Physical Chemistry C. 2011. Vol. 115. No. 50. pp. 24615-24620.
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Galakhov V. R., Buling A., Neumann M., Ovechkina N. A., Shkvarin A. S., Semenova A. S., Uimin M., Yermakov A., Kurmaev E. Z., Vilkov O. Y., Boukhvalov D. W. Carbon states in carbon-encapsulated nickel nanoparticles studied by means of X-ray absorption, emission, and photoelectron spectroscopies // Journal of Physical Chemistry C. 2011. Vol. 115. No. 50. pp. 24615-24620.
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RIS
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TY - JOUR
DO - 10.1021/jp2085846
UR - https://doi.org/10.1021/jp2085846
TI - Carbon states in carbon-encapsulated nickel nanoparticles studied by means of X-ray absorption, emission, and photoelectron spectroscopies
T2 - Journal of Physical Chemistry C
AU - Galakhov, V. R.
AU - Buling, A.
AU - Neumann, M.
AU - Ovechkina, N. A.
AU - Shkvarin, A. S.
AU - Semenova, A. S.
AU - Uimin, M.A.
AU - Yermakov, A.Ye.
AU - Kurmaev, E. Z.
AU - Vilkov, O. Yu.
AU - Boukhvalov, Danil W.
PY - 2011
DA - 2011/12/01
PB - American Chemical Society (ACS)
SP - 24615-24620
IS - 50
VL - 115
SN - 1932-7447
SN - 1932-7455
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Galakhov,
author = {V. R. Galakhov and A. Buling and M. Neumann and N. A. Ovechkina and A. S. Shkvarin and A. S. Semenova and M.A. Uimin and A.Ye. Yermakov and E. Z. Kurmaev and O. Yu. Vilkov and Danil W. Boukhvalov},
title = {Carbon states in carbon-encapsulated nickel nanoparticles studied by means of X-ray absorption, emission, and photoelectron spectroscopies},
journal = {Journal of Physical Chemistry C},
year = {2011},
volume = {115},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jp2085846},
number = {50},
pages = {24615--24620},
doi = {10.1021/jp2085846}
}
Cite this
MLA
Copy
Galakhov, V. R., et al. “Carbon states in carbon-encapsulated nickel nanoparticles studied by means of X-ray absorption, emission, and photoelectron spectroscopies.” Journal of Physical Chemistry C, vol. 115, no. 50, Dec. 2011, pp. 24615-24620. https://doi.org/10.1021/jp2085846.
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