Open Access
Lonsdaleite Films with Nanometer Thickness
Alexander G. Kvashnin
1, 2
,
Pavel B. Sorokin
1, 2, 3
Publication type: Journal Article
Publication date: 2014-01-24
scimago Q1
wos Q1
SJR: 1.394
CiteScore: 8.7
Impact factor: 4.6
ISSN: 19487185
PubMed ID:
26276606
Physical and Theoretical Chemistry
General Materials Science
Abstract
We investigate the properties of potentially the stiffest quasi-2-D films with lonsdaleite structure. Using a combination of ab initio and empirical potential approaches, we analyze the elastic properties of lonsdaleite films in both elastic and inelastic regimes and compare them with graphene and diamond films. We review possible fabrication methods of lonsdaleite films using the pure nanoscale "bottom-up" paradigm: by connecting carbon layers in multilayered graphene. We propose the realization of this method in two ways: by applying direct pressure and by using the recently proposed chemically induced phase transition. For both cases, we construct the phase diagrams depending on temperature, pressure, and film thickness. Finally, we consider the electronic properties of lonsdaleite films and establish the nonlinear dependence of the band gap on the films' thicknesses and their lower effective masses in comparison with bulk crystal.
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Metrics
63
Total citations:
63
Citations from 2024:
7
(11%)
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MLA
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GOST
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Kvashnin A. G. et al. Lonsdaleite Films with Nanometer Thickness // Journal of Physical Chemistry Letters. 2014. Vol. 5. No. 3. pp. 541-548.
GOST all authors (up to 50)
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Kvashnin A. G., Sorokin P. B. Lonsdaleite Films with Nanometer Thickness // Journal of Physical Chemistry Letters. 2014. Vol. 5. No. 3. pp. 541-548.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jz402528q
UR - https://doi.org/10.1021/jz402528q
TI - Lonsdaleite Films with Nanometer Thickness
T2 - Journal of Physical Chemistry Letters
AU - Kvashnin, Alexander G.
AU - Sorokin, Pavel B.
PY - 2014
DA - 2014/01/24
PB - American Chemical Society (ACS)
SP - 541-548
IS - 3
VL - 5
PMID - 26276606
SN - 1948-7185
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Kvashnin,
author = {Alexander G. Kvashnin and Pavel B. Sorokin},
title = {Lonsdaleite Films with Nanometer Thickness},
journal = {Journal of Physical Chemistry Letters},
year = {2014},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jz402528q},
number = {3},
pages = {541--548},
doi = {10.1021/jz402528q}
}
Cite this
MLA
Copy
Kvashnin, Alexander G., et al. “Lonsdaleite Films with Nanometer Thickness.” Journal of Physical Chemistry Letters, vol. 5, no. 3, Jan. 2014, pp. 541-548. https://doi.org/10.1021/jz402528q.