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Journal of Physical Chemistry Letters, volume 5, issue 3, pages 541-548

Lonsdaleite Films with Nanometer Thickness

Publication typeJournal Article
Publication date2014-01-24
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.7
ISSN19487185
Physical and Theoretical Chemistry
General Materials Science
Abstract
We investigate the properties of potentially the stiffest quasi-2-D films with lonsdaleite structure. Using a combination of ab initio and empirical potential approaches, we analyze the elastic properties of lonsdaleite films in both elastic and inelastic regimes and compare them with graphene and diamond films. We review possible fabrication methods of lonsdaleite films using the pure nanoscale "bottom-up" paradigm: by connecting carbon layers in multilayered graphene. We propose the realization of this method in two ways: by applying direct pressure and by using the recently proposed chemically induced phase transition. For both cases, we construct the phase diagrams depending on temperature, pressure, and film thickness. Finally, we consider the electronic properties of lonsdaleite films and establish the nonlinear dependence of the band gap on the films' thicknesses and their lower effective masses in comparison with bulk crystal.

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GOST |
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GOST Copy
Kvashnin A. G. et al. Lonsdaleite Films with Nanometer Thickness // Journal of Physical Chemistry Letters. 2014. Vol. 5. No. 3. pp. 541-548.
GOST all authors (up to 50) Copy
Kvashnin A. G., Sorokin P. B. Lonsdaleite Films with Nanometer Thickness // Journal of Physical Chemistry Letters. 2014. Vol. 5. No. 3. pp. 541-548.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jz402528q
UR - https://doi.org/10.1021%2Fjz402528q
TI - Lonsdaleite Films with Nanometer Thickness
T2 - Journal of Physical Chemistry Letters
AU - Kvashnin, Alexander G.
AU - Sorokin, Pavel B.
PY - 2014
DA - 2014/01/24 00:00:00
PB - American Chemical Society (ACS)
SP - 541-548
IS - 3
VL - 5
SN - 1948-7185
ER -
BibTex |
Cite this
BibTex Copy
@article{2014_Kvashnin,
author = {Alexander G. Kvashnin and Pavel B. Sorokin},
title = {Lonsdaleite Films with Nanometer Thickness},
journal = {Journal of Physical Chemistry Letters},
year = {2014},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021%2Fjz402528q},
number = {3},
pages = {541--548},
doi = {10.1021/jz402528q}
}
MLA
Cite this
MLA Copy
Kvashnin, Alexander G., et al. “Lonsdaleite Films with Nanometer Thickness.” Journal of Physical Chemistry Letters, vol. 5, no. 3, Jan. 2014, pp. 541-548. https://doi.org/10.1021%2Fjz402528q.
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