High-quality ultrathin polymer films obtained by deposition from supercritical carbon dioxide as imaged by atomic force microscopy
M. O. Gallyamov
1
,
Rostislav A Vinokur
1
,
Lev N Nikitin
1
,
Ernest E Said-Galiyev
1
,
Igor V. Yaminsky
1
,
Kjeld Schaumburg
1
Publication type: Journal Article
Publication date: 2002-08-09
scimago Q1
wos Q2
SJR: 0.763
CiteScore: 6.0
Impact factor: 3.9
ISSN: 07437463, 15205827
Spectroscopy
Electrochemistry
Condensed Matter Physics
General Materials Science
Surfaces and Interfaces
Abstract
Promising new technique of polymer deposition from solutions in supercritical carbon dioxide (sc CO2) has been applied to form ultrathin Teflon AF2400 copolymer films on substrates with different properties. Atomic force microscopy study of the coatings morphology has been performed for the first time and has revealed surprisingly high film uniformity, very low roughness, and good stability during the scanning procedure. Our findings have demonstrated the intriguing possibilities of the applied film-forming process allowing to deposit the thin-film coatings and also individual macromolecules in a controllable manner. This is because the variations of solution temperature and pressure influence significantly the dissolving power of sc CO2; therefore, the macromolecule precipitation depends strongly on the thermodynamic regime and can be easily controlled. The influence of substrate properties, exposure conditions, and deposition kinetics on the film morphology, thickness, and level of surface coverage has ...
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Total citations:
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Citations from 2024:
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(2%)
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GOST
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Gallyamov M. O. et al. High-quality ultrathin polymer films obtained by deposition from supercritical carbon dioxide as imaged by atomic force microscopy // Langmuir. 2002. Vol. 18. No. 18. pp. 6928-6934.
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Gallyamov M. O., Vinokur R. A., Nikitin L. N., Said-Galiyev E. E., Khokhlov A. R., Yaminsky I. V., Schaumburg K. High-quality ultrathin polymer films obtained by deposition from supercritical carbon dioxide as imaged by atomic force microscopy // Langmuir. 2002. Vol. 18. No. 18. pp. 6928-6934.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/la025807e
UR - https://doi.org/10.1021/la025807e
TI - High-quality ultrathin polymer films obtained by deposition from supercritical carbon dioxide as imaged by atomic force microscopy
T2 - Langmuir
AU - Gallyamov, M. O.
AU - Vinokur, Rostislav A
AU - Nikitin, Lev N
AU - Said-Galiyev, Ernest E
AU - Khokhlov, Alexei R.
AU - Yaminsky, Igor V.
AU - Schaumburg, Kjeld
PY - 2002
DA - 2002/08/09
PB - American Chemical Society (ACS)
SP - 6928-6934
IS - 18
VL - 18
SN - 0743-7463
SN - 1520-5827
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Gallyamov,
author = {M. O. Gallyamov and Rostislav A Vinokur and Lev N Nikitin and Ernest E Said-Galiyev and Alexei R. Khokhlov and Igor V. Yaminsky and Kjeld Schaumburg},
title = {High-quality ultrathin polymer films obtained by deposition from supercritical carbon dioxide as imaged by atomic force microscopy},
journal = {Langmuir},
year = {2002},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/la025807e},
number = {18},
pages = {6928--6934},
doi = {10.1021/la025807e}
}
Cite this
MLA
Copy
Gallyamov, M. O., et al. “High-quality ultrathin polymer films obtained by deposition from supercritical carbon dioxide as imaged by atomic force microscopy.” Langmuir, vol. 18, no. 18, Aug. 2002, pp. 6928-6934. https://doi.org/10.1021/la025807e.