Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: Stabilization and visualization
Publication type: Journal Article
Publication date: 2005-03-01
scimago Q1
wos Q2
SJR: 0.763
CiteScore: 6.0
Impact factor: 3.9
ISSN: 07437463, 15205827
PubMed ID:
15779928
Spectroscopy
Electrochemistry
Condensed Matter Physics
General Materials Science
Surfaces and Interfaces
Abstract
Formation of core-shell poly(N-vinylcaprolactam) (PVCL) single-molecule nanostructures due to interaction of PVCL with metal ions was studied using transmission electron microscopy, 13C NMR, and light scattering. This study demonstrates that addition of CoCl2 to PVCL in its globular conformation yields unimolecular core-shell polymer particles with the core decorated with Co(II) ions. The crucial condition for formation of well-defined unimolecular nanostructures is the presence of stable globular aggregates in aqueous solution. Moreover, the metal ions should have a sufficiently high coordination number (higher than 2) to provide a cross-linking and stabilization of the core.
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Bronstein L. M. et al. Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: Stabilization and visualization // Langmuir. 2005. Vol. 21. No. 7. pp. 2652-2655.
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Bronstein L. M., Kostylev M., Tsvetkova I., Tomaszewski J., Stein B., Makhaeva E. E., Okhapkin I., Khokhlov A. R. Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: Stabilization and visualization // Langmuir. 2005. Vol. 21. No. 7. pp. 2652-2655.
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TY - JOUR
DO - 10.1021/la047163b
UR - https://doi.org/10.1021/la047163b
TI - Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: Stabilization and visualization
T2 - Langmuir
AU - Bronstein, Lyudmila M
AU - Kostylev, Maxim
AU - Tsvetkova, Irina
AU - Tomaszewski, John
AU - Stein, Barry
AU - Makhaeva, Elena E.
AU - Okhapkin, Ivan
AU - Khokhlov, Alexei R.
PY - 2005
DA - 2005/03/01
PB - American Chemical Society (ACS)
SP - 2652-2655
IS - 7
VL - 21
PMID - 15779928
SN - 0743-7463
SN - 1520-5827
ER -
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BibTex (up to 50 authors)
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@article{2005_Bronstein,
author = {Lyudmila M Bronstein and Maxim Kostylev and Irina Tsvetkova and John Tomaszewski and Barry Stein and Elena E. Makhaeva and Ivan Okhapkin and Alexei R. Khokhlov},
title = {Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: Stabilization and visualization},
journal = {Langmuir},
year = {2005},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/la047163b},
number = {7},
pages = {2652--2655},
doi = {10.1021/la047163b}
}
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Bronstein, Lyudmila M., et al. “Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: Stabilization and visualization.” Langmuir, vol. 21, no. 7, Mar. 2005, pp. 2652-2655. https://doi.org/10.1021/la047163b.
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