Influence of migrating ionic groups on the solubility of polyelectrolytes: phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water
Publication type: Journal Article
Publication date: 2000-12-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The influence of the migration of charges bound to polymer chains on the solubility of the charged polymer is studied theoretically and experimentally. It is found that, due to the migration of charges, the solubility of such a polymer is lower than the solubility of a polyelectrolyte having the same fraction of nonmigrating charged groups. It is shown that the solubility of a copolymer with an ionizable component depends on the ratio of the degree of ionization i to the fraction x of monomer units B able to be ionized. If this ratio equals unity (i = x), the solubility of the copolymer increases with an increase in the fraction of monomer units B. When the fraction x of monomer units B is much higher than the actual degree of ionization i, the ions bound to the polymer chains can be easily transferred from one chain to another in an optimum way so that to minimize the loss in translational entropy of the counterions. As a result, demixing of the polymer solution for i ≠ x occurs at lower values of the po...
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
|
|
|
Langmuir
6 publications, 15.79%
|
|
|
Macromolecules
6 publications, 15.79%
|
|
|
European Polymer Journal
3 publications, 7.89%
|
|
|
Polymer Science - Series A
2 publications, 5.26%
|
|
|
Journal of Applied Polymer Science
2 publications, 5.26%
|
|
|
Industrial & Engineering Chemistry Research
2 publications, 5.26%
|
|
|
Polymer Science - Series C
1 publication, 2.63%
|
|
|
Macromolecular Chemistry and Physics
1 publication, 2.63%
|
|
|
Polymer
1 publication, 2.63%
|
|
|
Colloid and Polymer Science
1 publication, 2.63%
|
|
|
Progress in Polymer Science
1 publication, 2.63%
|
|
|
Polymer Degradation and Stability
1 publication, 2.63%
|
|
|
International Journal of Biological Macromolecules
1 publication, 2.63%
|
|
|
Journal of Colloid and Interface Science
1 publication, 2.63%
|
|
|
Chemistry - A European Journal
1 publication, 2.63%
|
|
|
Journal of Polymer Science, Part A: Polymer Chemistry
1 publication, 2.63%
|
|
|
ACS applied materials & interfaces
1 publication, 2.63%
|
|
|
Designed Monomers and Polymers
1 publication, 2.63%
|
|
|
1
2
3
4
5
6
|
Publishers
|
2
4
6
8
10
12
14
16
|
|
|
American Chemical Society (ACS)
15 publications, 39.47%
|
|
|
Elsevier
8 publications, 21.05%
|
|
|
Wiley
5 publications, 13.16%
|
|
|
Pleiades Publishing
3 publications, 7.89%
|
|
|
Springer Nature
1 publication, 2.63%
|
|
|
Taylor & Francis
1 publication, 2.63%
|
|
|
Society of Petroleum Engineers
1 publication, 2.63%
|
|
|
2
4
6
8
10
12
14
16
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
38
Total citations:
38
Citations from 2024:
0
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bokias G. et al. Influence of migrating ionic groups on the solubility of polyelectrolytes: phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water // Macromolecules. 2000. Vol. 33. No. 26. pp. 9757-9763.
GOST all authors (up to 50)
Copy
Bokias G., Vasilevskaya V. V., Iliopoulos I., Hourdet D., Khokhlov A. R. Influence of migrating ionic groups on the solubility of polyelectrolytes: phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water // Macromolecules. 2000. Vol. 33. No. 26. pp. 9757-9763.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma000413k
UR - https://doi.org/10.1021/ma000413k
TI - Influence of migrating ionic groups on the solubility of polyelectrolytes: phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water
T2 - Macromolecules
AU - Bokias, G.
AU - Vasilevskaya, V. V.
AU - Iliopoulos, I
AU - Hourdet, Dominique
AU - Khokhlov, Alexei R.
PY - 2000
DA - 2000/12/01
PB - American Chemical Society (ACS)
SP - 9757-9763
IS - 26
VL - 33
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2000_Bokias,
author = {G. Bokias and V. V. Vasilevskaya and I Iliopoulos and Dominique Hourdet and Alexei R. Khokhlov},
title = {Influence of migrating ionic groups on the solubility of polyelectrolytes: phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water},
journal = {Macromolecules},
year = {2000},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ma000413k},
number = {26},
pages = {9757--9763},
doi = {10.1021/ma000413k}
}
Cite this
MLA
Copy
Bokias, G., et al. “Influence of migrating ionic groups on the solubility of polyelectrolytes: phase behavior of ionic poly(N-isopropylacrylamide) copolymers in water.” Macromolecules, vol. 33, no. 26, Dec. 2000, pp. 9757-9763. https://doi.org/10.1021/ma000413k.