Polymers with Strongly Interacting Groups: Theory for Nonspherical Multiplets
Publication type: Journal Article
Publication date: 1995-10-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
A general theory for microstructure in systems of copolymers with strongly interacting groups (SIGs) is proposed. The so-called superstrong segregation limit, corresponding to rather short blocks containing SIGs and strong attraction between them, is considered in detail. In particular, multiplet formation in melts and solutions of ionomers (block ionomers) is studied. It is shown that as the interaction parameter increases, the most stable shape of a multiplet continuously changes from spherical to disklike (oblate ellipsoid). A further increase of the interaction parameter induces another (first order) transition from disklike multiplets to lamellae. The same transitions could be induced by decreasing the average length of ionic blocks in block ionomer systems. The relevant experimental observations are discussed.
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136
Total citations:
136
Citations from 2024:
7
(5.15%)
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Semenov A. N., Nyrkova I. A., Khokhlov A. R. Polymers with Strongly Interacting Groups: Theory for Nonspherical Multiplets // Macromolecules. 1995. Vol. 28. No. 22. pp. 7491-7500.
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Semenov A. N., Nyrkova I. A., Khokhlov A. R. Polymers with Strongly Interacting Groups: Theory for Nonspherical Multiplets // Macromolecules. 1995. Vol. 28. No. 22. pp. 7491-7500.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ma00126a029
UR - https://doi.org/10.1021/ma00126a029
TI - Polymers with Strongly Interacting Groups: Theory for Nonspherical Multiplets
T2 - Macromolecules
AU - Semenov, A. N.
AU - Nyrkova, I A
AU - Khokhlov, A R
PY - 1995
DA - 1995/10/01
PB - American Chemical Society (ACS)
SP - 7491-7500
IS - 22
VL - 28
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{1995_Semenov,
author = {A. N. Semenov and I A Nyrkova and A R Khokhlov},
title = {Polymers with Strongly Interacting Groups: Theory for Nonspherical Multiplets},
journal = {Macromolecules},
year = {1995},
volume = {28},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ma00126a029},
number = {22},
pages = {7491--7500},
doi = {10.1021/ma00126a029}
}
Cite this
MLA
Copy
Semenov, A. N., et al. “Polymers with Strongly Interacting Groups: Theory for Nonspherical Multiplets.” Macromolecules, vol. 28, no. 22, Oct. 1995, pp. 7491-7500. https://doi.org/10.1021/ma00126a029.
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