Domains in melts of comb-coil diblock copolymers: Superstrong segregation regime
Publication type: Journal Article
Publication date: 2001-06-06
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Conditions for the crossover from the strong to the superstrong segregation regime are analyzed for the case of comb−coil diblock copolymers. It is shown that the critical interaction energy between the components required to induce the crossover to the superstrong segregation regime is inversely proportional to mb = 1 + n/m, where n is the degree of polymerization of the side chain and m is the distance between successive grafting points. As a result, the superstrong segregation regime, being rather rare in the case of ordinary block copolymers, has a much better chance to be realized in the case of diblock copolymers with combs grafted to one of the blocks.
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Vasilevskaya V. V. et al. Domains in melts of comb-coil diblock copolymers: Superstrong segregation regime // Macromolecules. 2001. Vol. 34. No. 14. pp. 5019-5022.
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Vasilevskaya V. V., Gusev L. A., Khokhlov A. R., Ikkala O., ten Brinke G. Domains in melts of comb-coil diblock copolymers: Superstrong segregation regime // Macromolecules. 2001. Vol. 34. No. 14. pp. 5019-5022.
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TY - JOUR
DO - 10.1021/ma001621f
UR - https://doi.org/10.1021/ma001621f
TI - Domains in melts of comb-coil diblock copolymers: Superstrong segregation regime
T2 - Macromolecules
AU - Vasilevskaya, V V
AU - Gusev, L A
AU - Khokhlov, A R
AU - Ikkala, O
AU - ten Brinke, G.
PY - 2001
DA - 2001/06/06
PB - American Chemical Society (ACS)
SP - 5019-5022
IS - 14
VL - 34
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
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@article{2001_Vasilevskaya,
author = {V V Vasilevskaya and L A Gusev and A R Khokhlov and O Ikkala and G. ten Brinke},
title = {Domains in melts of comb-coil diblock copolymers: Superstrong segregation regime},
journal = {Macromolecules},
year = {2001},
volume = {34},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ma001621f},
number = {14},
pages = {5019--5022},
doi = {10.1021/ma001621f}
}
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MLA
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Vasilevskaya, V. V., et al. “Domains in melts of comb-coil diblock copolymers: Superstrong segregation regime.” Macromolecules, vol. 34, no. 14, Jun. 2001, pp. 5019-5022. https://doi.org/10.1021/ma001621f.