Self-organization in solutions of stiff-chain amphiphilic macromolecules
Publication type: Journal Article
Publication date: 2008-09-24
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Conformational properties of amphiphilic stiff-chain macromolecules in concentrated solutions in poor solvent have been studied via computer modeling. We have found that the conformational state of macromolecules in such systems depends on the macromolecular stiffness and on the way the solution has been prepared. Thus, if the concentration of globules increased from a very diluted solution, the globules remain stable, independent of the macromolecular stiffness, and do not aggregate even in concentrated solutions. On the other hand, if the solvent quality is gradually decreased in a solution with a concentration much larger than that of a semidilute solution, then relatively flexible chains form separate globules, whereas semirigid macromolecules tend to aggregate and form braid-like conformations. The results obtained agree with the published experimental data and can be used for directed synthesis of macromolecules modeling the behavior of biopolymers.
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Total citations:
27
Citations from 2024:
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GOST
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Vasilevskaya V. V. et al. Self-organization in solutions of stiff-chain amphiphilic macromolecules // Macromolecules. 2008. Vol. 41. No. 20. pp. 7722-7728.
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Vasilevskaya V. V., Markov V., ten Brinke G., Khokhlov A. R. Self-organization in solutions of stiff-chain amphiphilic macromolecules // Macromolecules. 2008. Vol. 41. No. 20. pp. 7722-7728.
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RIS
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TY - JOUR
DO - 10.1021/ma800465j
UR - https://doi.org/10.1021/ma800465j
TI - Self-organization in solutions of stiff-chain amphiphilic macromolecules
T2 - Macromolecules
AU - Vasilevskaya, V. V.
AU - Markov, V.A
AU - ten Brinke, G.
AU - Khokhlov, Alexei R.
PY - 2008
DA - 2008/09/24
PB - American Chemical Society (ACS)
SP - 7722-7728
IS - 20
VL - 41
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
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@article{2008_Vasilevskaya,
author = {V. V. Vasilevskaya and V.A Markov and G. ten Brinke and Alexei R. Khokhlov},
title = {Self-organization in solutions of stiff-chain amphiphilic macromolecules},
journal = {Macromolecules},
year = {2008},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ma800465j},
number = {20},
pages = {7722--7728},
doi = {10.1021/ma800465j}
}
Cite this
MLA
Copy
Vasilevskaya, V. V., et al. “Self-organization in solutions of stiff-chain amphiphilic macromolecules.” Macromolecules, vol. 41, no. 20, Sep. 2008, pp. 7722-7728. https://doi.org/10.1021/ma800465j.