Macromolecules

, том 29 , издание 9 , страницы 3167-3174

Diblock copolymers with a charged block in a selective solvent: Micellar structure

Тип публикации: Journal Article

Дата публикации: 1996-01-01

American Chemical Society (ACS)

Macromolecules

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wos Q1

БС1

SJR: 1.352

CiteScore: 9.0

Impact factor: 5.2

ISSN: 00249297, 15205835

DOI: 10.1021/ma9515745

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Materials Chemistry

Organic Chemistry

Inorganic Chemistry

Polymers and Plastics

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The structure of the micelles formed by a diblock copolymer with one neutral and one polyelectrolyte block dissolved in highly selective aqueous solutions is studied by the scaling method. In this case an insoluble neutral block forms the core of the micelle, while the corona consists of stretched polyelectrolyte chains. It is taken into account that the corona region can partially lose some of the counterions which can go to the outer solution; therefore the corona is always slightly charged. In some regimes the corona consists of two layers: the inner layer with the concentration blob structure and the outer layer with the electrostatic blob structure. The diagram of states showing different regimes of behavior of the micelles is constructed.

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10 цитирований

Хохлов Алексей

д.ф.-м.н., проф., академик, Российская академия наук

822 публикации, 21 447 цитирований

Индекс Хирша: 72

Московский государственный университет имени М.В. Ломоносова

Институт элементоорганических соединений им. А.Н. Несмеянова РАН

Области научных интересов

Наука о полимерах

Теория и компьютерное моделирование мягких сред

2 цитирования

Василевская Валентина

д.ф.-м.н., проф.

121 публикация, 2 523 цитирования, 59 рецензий

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Институт элементоорганических соединений им. А.Н. Несмеянова РАН

Области научных интересов

Высокомолекулярные соединения

Компьютерное моделирование

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Shusharina N. P., Nyrkova I. A., Khokhlov A. R. Diblock copolymers with a charged block in a selective solvent: Micellar structure // Macromolecules. 1996. Vol. 29. No. 9. pp. 3167-3174.

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Shusharina N. P., Nyrkova I. A., Khokhlov A. R. Diblock copolymers with a charged block in a selective solvent: Micellar structure // Macromolecules. 1996. Vol. 29. No. 9. pp. 3167-3174.

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TY - JOUR

DO - 10.1021/ma9515745

UR - https://doi.org/10.1021/ma9515745

TI - Diblock copolymers with a charged block in a selective solvent: Micellar structure

T2 - Macromolecules

AU - Shusharina, Nadezhda P

AU - Nyrkova, Irina A.

AU - Khokhlov, Alexei R.

PY - 1996

DA - 1996/01/01

PB - American Chemical Society (ACS)

SP - 3167-3174

IS - 9

VL - 29

SN - 0024-9297

SN - 1520-5835

ER -

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@article{1996_Shusharina,

author = {Nadezhda P Shusharina and Irina A. Nyrkova and Alexei R. Khokhlov},

title = {Diblock copolymers with a charged block in a selective solvent: Micellar structure},

journal = {Macromolecules},

year = {1996},

volume = {29},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://doi.org/10.1021/ma9515745},

number = {9},

pages = {3167--3174},

doi = {10.1021/ma9515745}

}

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Shusharina, Nadezhda P., et al. “Diblock copolymers with a charged block in a selective solvent: Micellar structure.” Macromolecules, vol. 29, no. 9, Jan. 1996, pp. 3167-3174. https://doi.org/10.1021/ma9515745.