Diblock copolymers with a charged block in a selective solvent: Micellar structure
Publication type: Journal Article
Publication date: 1996-01-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The structure of the micelles formed by a diblock copolymer with one neutral and one polyelectrolyte block dissolved in highly selective aqueous solutions is studied by the scaling method. In this case an insoluble neutral block forms the core of the micelle, while the corona consists of stretched polyelectrolyte chains. It is taken into account that the corona region can partially lose some of the counterions which can go to the outer solution; therefore the corona is always slightly charged. In some regimes the corona consists of two layers: the inner layer with the concentration blob structure and the outer layer with the electrostatic blob structure. The diagram of states showing different regimes of behavior of the micelles is constructed.
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78
Total citations:
78
Citations from 2024:
1
(1.3%)
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GOST
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Shusharina N. P., Nyrkova I. A., Khokhlov A. R. Diblock copolymers with a charged block in a selective solvent: Micellar structure // Macromolecules. 1996. Vol. 29. No. 9. pp. 3167-3174.
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Shusharina N. P., Nyrkova I. A., Khokhlov A. R. Diblock copolymers with a charged block in a selective solvent: Micellar structure // Macromolecules. 1996. Vol. 29. No. 9. pp. 3167-3174.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma9515745
UR - https://doi.org/10.1021/ma9515745
TI - Diblock copolymers with a charged block in a selective solvent: Micellar structure
T2 - Macromolecules
AU - Shusharina, Nadezhda P
AU - Nyrkova, Irina A.
AU - Khokhlov, Alexei R.
PY - 1996
DA - 1996/01/01
PB - American Chemical Society (ACS)
SP - 3167-3174
IS - 9
VL - 29
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1996_Shusharina,
author = {Nadezhda P Shusharina and Irina A. Nyrkova and Alexei R. Khokhlov},
title = {Diblock copolymers with a charged block in a selective solvent: Micellar structure},
journal = {Macromolecules},
year = {1996},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ma9515745},
number = {9},
pages = {3167--3174},
doi = {10.1021/ma9515745}
}
Cite this
MLA
Copy
Shusharina, Nadezhda P., et al. “Diblock copolymers with a charged block in a selective solvent: Micellar structure.” Macromolecules, vol. 29, no. 9, Jan. 1996, pp. 3167-3174. https://doi.org/10.1021/ma9515745.
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