Collapse of polyelectrolyte macromolecules revisited
Тип публикации: Journal Article
Дата публикации: 1997-06-01
scimago Q1
wos Q1
БС1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
The simplest theory of the collapse transition of single polyelectrolyte chains in dilute solutions is reconsidered. A novel feature of the new treatment is that the counterions can either remain within the coil or float in the outer solution. It is shown that the latter possibility is realized in many cases; thus, for these situations, the electrostatic repulsion between the uncompensated charges plays an important role in the chain behavior. These uncompensated charges lead to a significant difference between the collapse behavior of single chains and macroscopic gels where electrostatic repulsion is normally negligible and the swelling is mainly due to the osmotic pressure of counterions kept inside the gel sample. In addition the intermediate case of microgel particles of different molecular masses is considered, and the role of counterion redistribution between polymer and solution is investigated.
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ГОСТ
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Kramarenko E., Khokhlov A. R., Yoshikawa K. Collapse of polyelectrolyte macromolecules revisited // Macromolecules. 1997. Vol. 30. No. 11. pp. 3383-3388.
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Kramarenko E., Khokhlov A. R., Yoshikawa K. Collapse of polyelectrolyte macromolecules revisited // Macromolecules. 1997. Vol. 30. No. 11. pp. 3383-3388.
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TY - JOUR
DO - 10.1021/ma961126c
UR - https://doi.org/10.1021/ma961126c
TI - Collapse of polyelectrolyte macromolecules revisited
T2 - Macromolecules
AU - Kramarenko, E.Yu.
AU - Khokhlov, Alexei R.
AU - Yoshikawa, K.
PY - 1997
DA - 1997/06/01
PB - American Chemical Society (ACS)
SP - 3383-3388
IS - 11
VL - 30
SN - 0024-9297
SN - 1520-5835
ER -
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@article{1997_Kramarenko,
author = {E.Yu. Kramarenko and Alexei R. Khokhlov and K. Yoshikawa},
title = {Collapse of polyelectrolyte macromolecules revisited},
journal = {Macromolecules},
year = {1997},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ma961126c},
number = {11},
pages = {3383--3388},
doi = {10.1021/ma961126c}
}
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MLA
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Kramarenko, E.Yu., et al. “Collapse of polyelectrolyte macromolecules revisited.” Macromolecules, vol. 30, no. 11, Jun. 1997, pp. 3383-3388. https://doi.org/10.1021/ma961126c.
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