volume 31 issue 18 pages 6112-6118

Conformational changes of poly(vinylcaprolactam) macromolecules and their complexes with ionic surfactants in aqueous solution

Publication typeJournal Article
Publication date1998-08-19
scimago Q1
wos Q1
SJR1.352
CiteScore9.0
Impact factor5.2
ISSN00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Dynamic light scattering measurements have been performed for aqueous solutions of linear poly(vinylcaprolactam) (PVCa) at several polymer concentrations and over a wide range of ionic surfactant concentration. The intermolecular aggregation of PVCa accompanied by a sharp increase of the light scattering intensity is observed in pure water at 33 °C. The effect of ionic surfactants (cetylpyridinium chloride (CPC) and sodium dodecyl sulfate (SDS)) on the behavior of solutions of linear PVCa was studied as a function of temperature. For polymer concentrations below the overlap concentration (2.5 mg/mL) a decrease of the macromolecular hydrodynamic diameter is observed upon the addition of ionic surfactant (SDS, CPC) at low surfactant concentrations. This effect is in contrast to the behavior of the complexes of surfactant with another thermosensitive polymer, poly(N-isopropylacrylamide) (PNIPA). A further increase of the surfactant concentration leads to the reentrant swelling of macromolecules. In the prese...
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GOST Copy
Makhaeva E. E., Tenhu H., Khokhlov A. R. Conformational changes of poly(vinylcaprolactam) macromolecules and their complexes with ionic surfactants in aqueous solution // Macromolecules. 1998. Vol. 31. No. 18. pp. 6112-6118.
GOST all authors (up to 50) Copy
Makhaeva E. E., Tenhu H., Khokhlov A. R. Conformational changes of poly(vinylcaprolactam) macromolecules and their complexes with ionic surfactants in aqueous solution // Macromolecules. 1998. Vol. 31. No. 18. pp. 6112-6118.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ma980158s
UR - https://doi.org/10.1021/ma980158s
TI - Conformational changes of poly(vinylcaprolactam) macromolecules and their complexes with ionic surfactants in aqueous solution
T2 - Macromolecules
AU - Makhaeva, Elena E.
AU - Tenhu, Heikki
AU - Khokhlov, Alexei R.
PY - 1998
DA - 1998/08/19
PB - American Chemical Society (ACS)
SP - 6112-6118
IS - 18
VL - 31
SN - 0024-9297
SN - 1520-5835
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1998_Makhaeva,
author = {Elena E. Makhaeva and Heikki Tenhu and Alexei R. Khokhlov},
title = {Conformational changes of poly(vinylcaprolactam) macromolecules and their complexes with ionic surfactants in aqueous solution},
journal = {Macromolecules},
year = {1998},
volume = {31},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ma980158s},
number = {18},
pages = {6112--6118},
doi = {10.1021/ma980158s}
}
MLA
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MLA Copy
Makhaeva, Elena E., et al. “Conformational changes of poly(vinylcaprolactam) macromolecules and their complexes with ionic surfactants in aqueous solution.” Macromolecules, vol. 31, no. 18, Aug. 1998, pp. 6112-6118. https://doi.org/10.1021/ma980158s.