Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes
Тип публикации: Journal Article
Дата публикации: 2000-04-06
scimago Q1
wos Q1
БС1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
Using pyrene and homologous alkyl derivatives of fluorescein as fluorescent probes, this work examines the partitioning coefficients of hydrophobic solutes in aqueous dispersions of Pluronic block copolymers (poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide)). An incremental approach is developed, allowing measurement of the free energy of transfer of a methylene group from aqueous media into the micelles. Effects of variation of length of the ethylene oxide (EO) and the propylene oxide (PO) blocks in Pluronic molecules on the partitioning characteristics of the solutes are established. A simple reciprocal relationship between partitioning coefficients of the solute and critical micellization concentration is demonstrated.
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Kozlov M. Yu. et al. Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes // Macromolecules. 2000. Vol. 33. No. 9. pp. 3305-3313.
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Kozlov M. Yu., Melik-Nubarov N. S., Batrakova E. V., Kabanov A. Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes // Macromolecules. 2000. Vol. 33. No. 9. pp. 3305-3313.
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TY - JOUR
DO - 10.1021/ma991634x
UR - https://pubs.acs.org/doi/10.1021/ma991634x
TI - Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes
T2 - Macromolecules
AU - Kozlov, Mikhail Yu
AU - Melik-Nubarov, Nikolai S.
AU - Batrakova, Elena V
AU - Kabanov, A.A.
PY - 2000
DA - 2000/04/06
PB - American Chemical Society (ACS)
SP - 3305-3313
IS - 9
VL - 33
SN - 0024-9297
SN - 1520-5835
ER -
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@article{2000_Kozlov,
author = {Mikhail Yu Kozlov and Nikolai S. Melik-Nubarov and Elena V Batrakova and A.A. Kabanov},
title = {Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes},
journal = {Macromolecules},
year = {2000},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://pubs.acs.org/doi/10.1021/ma991634x},
number = {9},
pages = {3305--3313},
doi = {10.1021/ma991634x}
}
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Kozlov, Mikhail Yu., et al. “Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes.” Macromolecules, vol. 33, no. 9, Apr. 2000, pp. 3305-3313. https://pubs.acs.org/doi/10.1021/ma991634x.
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