, volume 33 , issue 9 , pages 3305-3313

Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes

Mikhail Yu Kozlov ¹

Nikolai S Melik Nubarov ¹

Elena V Batrakova ¹

A.A. Kabanov ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Polymer Science, M.V. Lomonosov Moscow State University, Leniskie Gory, Moscow V-234, 119899, Russia; and College of Pharmacy, Department of Pharmaceutical Sciences, 986025 University of Nebraska Medical Center, Omaha, Nebraska 68198-6025 |

Publication type: Journal Article

Publication date: 2000-04-06

American Chemical Society (ACS)

Macromolecules

scimago Q1

wos Q1

SJR: 1.352

CiteScore: 9.0

Impact factor: 5.2

ISSN: 00249297, 15205835

DOI: 10.1021/ma991634x

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Materials Chemistry

Organic Chemistry

Inorganic Chemistry

Polymers and Plastics

Abstract

Using pyrene and homologous alkyl derivatives of fluorescein as fluorescent probes, this work examines the partitioning coefficients of hydrophobic solutes in aqueous dispersions of Pluronic block copolymers (poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide)). An incremental approach is developed, allowing measurement of the free energy of transfer of a methylene group from aqueous media into the micelles. Effects of variation of length of the ethylene oxide (EO) and the propylene oxide (PO) blocks in Pluronic molecules on the partitioning characteristics of the solutes are established. A simple reciprocal relationship between partitioning coefficients of the solute and critical micellization concentration is demonstrated.

Found

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Melik-Nubarov Nikolay

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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan National Research Technological University

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Iakimov Nikolai

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1 citation

Chernysheva Maria

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h-index: 15

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Gusliakova Olga

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Skolkovo Institute of Science and Technology

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Levit Galina

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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

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Zhilytsova Elena

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A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

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Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry of the Russian Academy of Sciences

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Kozlov M. Yu. et al. Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes // Macromolecules. 2000. Vol. 33. No. 9. pp. 3305-3313.

GOST all authors (up to 50) Copy

Kozlov M. Yu., Melik Nubarov N. S., Batrakova E. V., Kabanov A. Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes // Macromolecules. 2000. Vol. 33. No. 9. pp. 3305-3313.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/ma991634x

UR - https://doi.org/10.1021/ma991634x

TI - Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes

T2 - Macromolecules

AU - Kozlov, Mikhail Yu

AU - Melik Nubarov, Nikolai S

AU - Batrakova, Elena V

AU - Kabanov, A.A.

PY - 2000

DA - 2000/04/06

PB - American Chemical Society (ACS)

SP - 3305-3313

IS - 9

VL - 33

SN - 0024-9297

SN - 1520-5835

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2000_Kozlov,

author = {Mikhail Yu Kozlov and Nikolai S Melik Nubarov and Elena V Batrakova and A.A. Kabanov},

title = {Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes},

journal = {Macromolecules},

year = {2000},

volume = {33},

publisher = {American Chemical Society (ACS)},

month = {apr},

url = {https://doi.org/10.1021/ma991634x},

number = {9},

pages = {3305--3313},

doi = {10.1021/ma991634x}

}

MLA

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MLA Copy

Kozlov, Mikhail Yu., et al. “Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes.” Macromolecules, vol. 33, no. 9, Apr. 2000, pp. 3305-3313. https://doi.org/10.1021/ma991634x.