Micelles of diblock copolymers with charged and neutral blocks: Scaling and mean-field lattice approaches
Publication type: Journal Article
Publication date: 2000-04-29
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Polymer micelles composed of block copolymers with one charged and one neutral block in aqueous salt free solution are analyzed by scaling and mean-field lattice theory. We study the micellar structure as a function of the length of the both blocks and the fractional charge of the hydrophilic block. The diagram of the different regimes of the behavior of the equilibrium micellar sizes is constructed. The distribution of the counterions in the system is examined using the scaling and the mean-field approaches. The numerical mean-field results are found to be consistent with three scaling regimes: a quasineutral at small fractional charge, the “Pincus” regime where the Coulomb interaction in the corona is unscreened since the counterions are located outside the corona region, and an osmotic regime where the Coulomb interactions are screened by counterions located in the corona region.
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34
Total citations:
34
Citations from 2024:
2
(5.88%)
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GOST
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Shusharina N. P., Linse P., Khokhlov A. R. Micelles of diblock copolymers with charged and neutral blocks: Scaling and mean-field lattice approaches // Macromolecules. 2000. Vol. 33. No. 10. pp. 3892-3901.
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Shusharina N. P., Linse P., Khokhlov A. R. Micelles of diblock copolymers with charged and neutral blocks: Scaling and mean-field lattice approaches // Macromolecules. 2000. Vol. 33. No. 10. pp. 3892-3901.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ma9917491
UR - https://doi.org/10.1021/ma9917491
TI - Micelles of diblock copolymers with charged and neutral blocks: Scaling and mean-field lattice approaches
T2 - Macromolecules
AU - Shusharina, Nadezhda P
AU - Linse, Per
AU - Khokhlov, Alexei R.
PY - 2000
DA - 2000/04/29
PB - American Chemical Society (ACS)
SP - 3892-3901
IS - 10
VL - 33
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2000_Shusharina,
author = {Nadezhda P Shusharina and Per Linse and Alexei R. Khokhlov},
title = {Micelles of diblock copolymers with charged and neutral blocks: Scaling and mean-field lattice approaches},
journal = {Macromolecules},
year = {2000},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ma9917491},
number = {10},
pages = {3892--3901},
doi = {10.1021/ma9917491}
}
Cite this
MLA
Copy
Shusharina, Nadezhda P., et al. “Micelles of diblock copolymers with charged and neutral blocks: Scaling and mean-field lattice approaches.” Macromolecules, vol. 33, no. 10, Apr. 2000, pp. 3892-3901. https://doi.org/10.1021/ma9917491.
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