Absolute Configuration of Brevisamide and Brevisin: Confirmation of a Universal Biosynthetic Process for Karenia brevis Polyethers
Тип публикации: Journal Article
Дата публикации: 2010-06-07
scimago Q1
wos Q1
white level БС1
SJR: 0.629
CiteScore: 6.5
Impact factor: 3.6
ISSN: 01633864, 15206025
PubMed ID:
20527743
Organic Chemistry
Drug Discovery
Pharmacology
Pharmaceutical Science
Molecular Medicine
Complementary and alternative medicine
Analytical Chemistry
Краткое описание
The discovery of brevisin, the first example of an "interrupted" polycyclic ether, obtained from the dinoflagellate Karenia brevis, posed some important questions regarding the mechanism of the cyclization process. Consequently, we have established absolute configurations of brevisin and its related metabolite brevisamide using a modified Mosher's esterification method. For brevisin, analysis was carried out on both the 31-monokis- and the 10,31-bis-MTPA esters. The results suggest that both metabolites, like other polyethers from K. brevis, result from polyepoxide precursors with uniform (S, S) configurations for all epoxides and provide further support for a universal stereochemical model for dinoflagellate polyether formation.
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ГОСТ
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Van Wagoner R. M. et al. Absolute Configuration of Brevisamide and Brevisin: Confirmation of a Universal Biosynthetic Process for Karenia brevis Polyethers // Journal of Natural Products. 2010. Vol. 73. No. 6. pp. 1177-1179.
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Van Wagoner R. M., Satake M., Bourdelais A. J., Baden D. G., Wright J. L. C. Absolute Configuration of Brevisamide and Brevisin: Confirmation of a Universal Biosynthetic Process for Karenia brevis Polyethers // Journal of Natural Products. 2010. Vol. 73. No. 6. pp. 1177-1179.
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RIS
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TY - JOUR
DO - 10.1021/np100159j
UR - https://doi.org/10.1021/np100159j
TI - Absolute Configuration of Brevisamide and Brevisin: Confirmation of a Universal Biosynthetic Process for Karenia brevis Polyethers
T2 - Journal of Natural Products
AU - Van Wagoner, Ryan M.
AU - Satake, Masayuki
AU - Bourdelais, Andrea J.
AU - Baden, Daniel G.
AU - Wright, Jeffrey L C
PY - 2010
DA - 2010/06/07
PB - American Chemical Society (ACS)
SP - 1177-1179
IS - 6
VL - 73
PMID - 20527743
SN - 0163-3864
SN - 1520-6025
ER -
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BibTex (до 50 авторов)
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@article{2010_Van Wagoner,
author = {Ryan M. Van Wagoner and Masayuki Satake and Andrea J. Bourdelais and Daniel G. Baden and Jeffrey L C Wright},
title = {Absolute Configuration of Brevisamide and Brevisin: Confirmation of a Universal Biosynthetic Process for Karenia brevis Polyethers},
journal = {Journal of Natural Products},
year = {2010},
volume = {73},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/np100159j},
number = {6},
pages = {1177--1179},
doi = {10.1021/np100159j}
}
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MLA
Скопировать
Van Wagoner, Ryan M., et al. “Absolute Configuration of Brevisamide and Brevisin: Confirmation of a Universal Biosynthetic Process for Karenia brevis Polyethers.” Journal of Natural Products, vol. 73, no. 6, Jun. 2010, pp. 1177-1179. https://doi.org/10.1021/np100159j.
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