The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry
Publication type: Journal Article
Publication date: 2003-12-23
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
14723515
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
[reaction: see text] The first total synthesis of 15-deoxy-Delta12,14-prostaglandin J2 is reported. The highly unsaturated cyclopentenone prostaglandin was obtained via a silicon-tethered allenic [2 + 2 + 1] cycloaddition reaction developed in our group. In addition, the stereochemistry at C14 has been assigned unambiguously.
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49
Total citations:
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Citations from 2025:
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(2.04%)
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GOST
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Brummond K. M., Sill P. C., Chen H. The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry // Organic Letters. 2003. Vol. 6. No. 2. pp. 149-152.
GOST all authors (up to 50)
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Brummond K. M., Sill P. C., Chen H. The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry // Organic Letters. 2003. Vol. 6. No. 2. pp. 149-152.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol035590v
UR - https://doi.org/10.1021/ol035590v
TI - The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry
T2 - Organic Letters
AU - Brummond, Kay M.
AU - Sill, Peter C.
AU - Chen, Hongfeng
PY - 2003
DA - 2003/12/23
PB - American Chemical Society (ACS)
SP - 149-152
IS - 2
VL - 6
PMID - 14723515
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2003_Brummond,
author = {Kay M. Brummond and Peter C. Sill and Hongfeng Chen},
title = {The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry},
journal = {Organic Letters},
year = {2003},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ol035590v},
number = {2},
pages = {149--152},
doi = {10.1021/ol035590v}
}
Cite this
MLA
Copy
Brummond, Kay M., et al. “The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry.” Organic Letters, vol. 6, no. 2, Dec. 2003, pp. 149-152. https://doi.org/10.1021/ol035590v.