Organic Letters

, том 6 , издание 2 , страницы 149-152

The First Total Synthesis of 15-Deoxy-Δ^12,14-prostaglandin J₂ and the Unambiguous Assignment of the C¹⁴ Stereochemistry

Тип публикации: Journal Article

Дата публикации: 2003-12-23

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

БС1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/ol035590v

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PubMed ID: 14723515

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

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[reaction: see text] The first total synthesis of 15-deoxy-Delta12,14-prostaglandin J2 is reported. The highly unsaturated cyclopentenone prostaglandin was obtained via a silicon-tethered allenic [2 + 2 + 1] cycloaddition reaction developed in our group. In addition, the stereochemistry at C14 has been assigned unambiguously.

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Brummond K. M., Sill P. C., Chen H. The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry // Organic Letters. 2003. Vol. 6. No. 2. pp. 149-152.

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TY - JOUR

DO - 10.1021/ol035590v

UR - https://doi.org/10.1021/ol035590v

TI - The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry

T2 - Organic Letters

AU - Brummond, Kay M.

AU - Sill, Peter C.

AU - Chen, Hongfeng

PY - 2003

DA - 2003/12/23

PB - American Chemical Society (ACS)

SP - 149-152

IS - 2

VL - 6

PMID - 14723515

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2003_Brummond,

author = {Kay M. Brummond and Peter C. Sill and Hongfeng Chen},

title = {The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry},

journal = {Organic Letters},

year = {2003},

volume = {6},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/ol035590v},

number = {2},

pages = {149--152},

doi = {10.1021/ol035590v}

}

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Brummond, Kay M., et al. “The First Total Synthesis of 15-Deoxy-Δ12,14-prostaglandin J2 and the Unambiguous Assignment of the C14 Stereochemistry.” Organic Letters, vol. 6, no. 2, Dec. 2003, pp. 149-152. https://doi.org/10.1021/ol035590v.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

scimago Q1

wos Q1

БС1

SJR

1.235

CiteScore

8.7

Impact factor

ISSN

15237060 (Print)

15237052 (Electronic)