volume 14 issue 3 pages 930-933

Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages

Publication typeJournal Article
Publication date2012-01-24
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
PubMed ID:  22273364
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An inexpensive cationic ruthenium(II) catalyst enabled the expedient synthesis of isocoumarins through oxidative annulations of alkynes by benzoic acids. This C-H/O-H bond functionalization process also proved applicable to the preparation of α-pyrones and was shown to proceed by rate-limiting C-H bond ruthenation.
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GOST |
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GOST Copy
Ackermann L. et al. Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages // Organic Letters. 2012. Vol. 14. No. 3. pp. 930-933.
GOST all authors (up to 50) Copy
Ackermann L., Pospech J., Graczyk K., Rauch K. Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages // Organic Letters. 2012. Vol. 14. No. 3. pp. 930-933.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ol2034614
UR - https://doi.org/10.1021/ol2034614
TI - Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages
T2 - Organic Letters
AU - Ackermann, Lutz
AU - Pospech, J.
AU - Graczyk, Karolina
AU - Rauch, Karsten
PY - 2012
DA - 2012/01/24
PB - American Chemical Society (ACS)
SP - 930-933
IS - 3
VL - 14
PMID - 22273364
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Ackermann,
author = {Lutz Ackermann and J. Pospech and Karolina Graczyk and Karsten Rauch},
title = {Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages},
journal = {Organic Letters},
year = {2012},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ol2034614},
number = {3},
pages = {930--933},
doi = {10.1021/ol2034614}
}
MLA
Cite this
MLA Copy
Ackermann, Lutz, et al. “Versatile Synthesis of Isocoumarins and α-Pyrones by Ruthenium-Catalyzed Oxidative C–H/O–H Bond Cleavages.” Organic Letters, vol. 14, no. 3, Jan. 2012, pp. 930-933. https://doi.org/10.1021/ol2034614.