Synthesis, Characterization, and Reactivity of N-Heterocyclic Carbene Palladium(II) Hydroxide Dimers
Publication type: Journal Article
Publication date: 2011-08-03
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Palladium hydroxide dimers were prepared by reactions of CsOH with monomeric [Pd(NHC)(η3-allyl)Cl] starting materials. The dimers represent species proposed as intermediates in important cross-coupling reactions. These complexes were tested for their catalytic activity in Suzuki–Miyaura coupling and Buchwald–Hartwig aryl amination. The hydroxide complexes were susceptible to hydrogenolysis on exposure to H2 gas. Following H2O elimination and β-hydride elimination of an additional cinnamyl ligand, a Pd(0) species is formed which can react with other available ligands.
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44
Total citations:
44
Citations from 2025:
2
(4.55%)
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GOST
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Egbert J. et al. Synthesis, Characterization, and Reactivity of N-Heterocyclic Carbene Palladium(II) Hydroxide Dimers // Organometallics. 2011. Vol. 30. No. 17. pp. 4494-4496.
GOST all authors (up to 50)
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Egbert J., Chartoire A., Slawin A. M. Z., Nolan S. P. Synthesis, Characterization, and Reactivity of N-Heterocyclic Carbene Palladium(II) Hydroxide Dimers // Organometallics. 2011. Vol. 30. No. 17. pp. 4494-4496.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/om200579h
UR - https://doi.org/10.1021/om200579h
TI - Synthesis, Characterization, and Reactivity of N-Heterocyclic Carbene Palladium(II) Hydroxide Dimers
T2 - Organometallics
AU - Egbert, Jonathan
AU - Chartoire, Anthony
AU - Slawin, Alexandra M. Z.
AU - Nolan, Steven P.
PY - 2011
DA - 2011/08/03
PB - American Chemical Society (ACS)
SP - 4494-4496
IS - 17
VL - 30
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Egbert,
author = {Jonathan Egbert and Anthony Chartoire and Alexandra M. Z. Slawin and Steven P. Nolan},
title = {Synthesis, Characterization, and Reactivity of N-Heterocyclic Carbene Palladium(II) Hydroxide Dimers},
journal = {Organometallics},
year = {2011},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/om200579h},
number = {17},
pages = {4494--4496},
doi = {10.1021/om200579h}
}
Cite this
MLA
Copy
Egbert, Jonathan, et al. “Synthesis, Characterization, and Reactivity of N-Heterocyclic Carbene Palladium(II) Hydroxide Dimers.” Organometallics, vol. 30, no. 17, Aug. 2011, pp. 4494-4496. https://doi.org/10.1021/om200579h.