How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study
E I Gutsul
1
,
N. V. Belkova
1
,
G M Babakhina
1
,
L M Epstein
1
,
E. S. Shubina
1
,
C. Bianchini
2
,
M. Peruzzini
2
,
F. Zanobini
2
Publication type: Journal Article
Publication date: 2003-09-15
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
According to low-temperature UV-Vis spectroscopy data, the two-step protonation of iron subgroup metal hydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os) with p-nitrophenol includes the formation of ion pairs stabilized by a hydrogen bond between the cationic dihydrogen complex and the phenolate anion. The trend of the extent of proton transfer appeared to be aperiodic, FeI ≪ OsI < RuI, in contrast to the previously obtained sequence of the proton-acceptor capacity of the hydride ligand, which increases down the group.
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Gutsul E. I. et al. How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study // Russian Chemical Bulletin. 2003. Vol. 52. No. 5. pp. 1204-1206.
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Gutsul E. I., Belkova N. V., Babakhina G. M., Epstein L. M., Shubina E. S., Bianchini C., Peruzzini M., Zanobini F. How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study // Russian Chemical Bulletin. 2003. Vol. 52. No. 5. pp. 1204-1206.
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RIS
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TY - JOUR
DO - 10.1023/A:1024786030162
UR - https://doi.org/10.1023/A:1024786030162
TI - How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study
T2 - Russian Chemical Bulletin
AU - Gutsul, E I
AU - Belkova, N. V.
AU - Babakhina, G M
AU - Epstein, L M
AU - Shubina, E. S.
AU - Bianchini, C.
AU - Peruzzini, M.
AU - Zanobini, F.
PY - 2003
DA - 2003/09/15
PB - Springer Nature
SP - 1204-1206
IS - 5
VL - 52
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2003_Gutsul,
author = {E I Gutsul and N. V. Belkova and G M Babakhina and L M Epstein and E. S. Shubina and C. Bianchini and M. Peruzzini and F. Zanobini},
title = {How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study},
journal = {Russian Chemical Bulletin},
year = {2003},
volume = {52},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1023/A:1024786030162},
number = {5},
pages = {1204--1206},
doi = {10.1023/A:1024786030162}
}
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MLA
Copy
Gutsul, E. I., et al. “How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study.” Russian Chemical Bulletin, vol. 52, no. 5, Sep. 2003, pp. 1204-1206. https://doi.org/10.1023/A:1024786030162.
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