Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal
J. Andrieu
1
,
N. V. Belkova
2
,
M Besora
3
,
E Collange
1
,
L M Epstein
2
,
A. Lledós
3
,
R. Poli
1
,
P O Revin
1, 2
,
E. S. Shubina
2
,
E.V. Vorontsov
2
Publication type: Journal Article
Publication date: 2003-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The protonation of complexes Cp*M(dppe)H3 (dppe is ethylenebis(diphenylphosphine), M = Mo (1), W (2)) by a variety of fluorinated alcohols of different acid strength (FCH2CH2OH, CF3CH2OH, (CF3)2CHOH, and (CF3)3COH) was investigated experimentally by the variable temperature spectroscopic methods (IR, NMR) and stopped-flow technique (UV-Vis). The structures of the hydrogen-bonded and proton transfer products were studied by DFT calculations. In agreement with the calculation results, the IR data suggest that the initial hydrogen bond is established with a hydride site for complex 1 and with the metal site for complex 2. However, no intermediate dihydrogen complex found theoretically was detected experimentally on the way to the final classical tetrahydride product.
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Andrieu J. et al. Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal // Russian Chemical Bulletin. 2003. Vol. 52. No. 12. pp. 2679-2682.
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Andrieu J., Belkova N. V., Besora M., Collange E., Epstein L. M., Lledós A., Poli R., Revin P. O., Shubina E. S., Vorontsov E. Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal // Russian Chemical Bulletin. 2003. Vol. 52. No. 12. pp. 2679-2682.
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TY - JOUR
DO - 10.1023/B:RUCB.0000019886.18334.55
UR - https://doi.org/10.1023/B:RUCB.0000019886.18334.55
TI - Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal
T2 - Russian Chemical Bulletin
AU - Andrieu, J.
AU - Belkova, N. V.
AU - Besora, M
AU - Collange, E
AU - Epstein, L M
AU - Lledós, A.
AU - Poli, R.
AU - Revin, P O
AU - Shubina, E. S.
AU - Vorontsov, E.V.
PY - 2003
DA - 2003/12/01
PB - Springer Nature
SP - 2679-2682
IS - 12
VL - 52
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2003_Andrieu,
author = {J. Andrieu and N. V. Belkova and M Besora and E Collange and L M Epstein and A. Lledós and R. Poli and P O Revin and E. S. Shubina and E.V. Vorontsov},
title = {Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal},
journal = {Russian Chemical Bulletin},
year = {2003},
volume = {52},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1023/B:RUCB.0000019886.18334.55},
number = {12},
pages = {2679--2682},
doi = {10.1023/B:RUCB.0000019886.18334.55}
}
Cite this
MLA
Copy
Andrieu, J., et al. “Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H3(M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal.” Russian Chemical Bulletin, vol. 52, no. 12, Dec. 2003, pp. 2679-2682. https://doi.org/10.1023/B:RUCB.0000019886.18334.55.
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