Open Access

Scientific Reports, volume 8, issue 1, publication number 3663

High-resolution 3D photopolymerization assisted by upconversion nanoparticles for rapid prototyping applications

Rocheva Vasilina V ¹

Koroleva Anastasia V ^{2, 3}

Savelyev A.G. ^{1, 2}

Khaydukov Kirill V. ¹

Generalova Alla N ^{1, 4}

Nechaev Andrey V. ^{1, 5}

Guller Anna ^{2, 6}

Semchishen Vladimir A ¹

Chichkov Boris N. ^{1, 3, 7}

Khaydukov Evgeny V. ^{1, 2, 8}

Hide authors affiliations Show authors affiliations: 8 affiliations

Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences, Moscow, Russia |

Sechenov first moscow state medical university, Moscow, Russia |

Laser Zentrum Hannover, Hannover, Germany |

⁴

Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry of the Russian Academy of Sciences, Moscow, Russia |

⁵

Institute of Fine Chemical Technologies, Moscow Technological University, Moscow, Russia |

⁶

MACQUARIE UNIVERSITY, SYDNEY, AUSTRALIA |

⁷

Institut Für Quantenoptik, Leibniz Universität Hannover, Hannover, Germany |

⁸

International Joint Center for Biomedical Innovation, School of Life Sciences, Henan University, Kaifeng, China |

Publication type: Journal Article

Publication date: 2018-02-26

Springer Nature

Journal: Scientific Reports

Quartile SCImago

Quartile WOS

Impact factor: 4.6

ISSN: 20452322

DOI: 10.1038/s41598-018-21793-0

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Multidisciplinary

Abstract

Three-dimensional (3D) rapid prototyping technology based on near-infrared light-induced polymerization of photocurable compositions containing upconversion nanomaterials has been explored. For this aim, the rationally-designed core/shell upconversion nanoparticles NaYF4:Yb3+,Tm3+/NaYF4, with the distinct ultraviolet-emitting lines and unprecedentedly high near-infrared to ultraviolet conversion efficiency of $${\eta }_{{\bf{UC}}}^{({\bf{UV}})}=2{\boldsymbol{ \% }}$$ have been used. The upconverted ultraviolet photons were capable to efficiently activate photoinitiators contained in light-sensitive resins under moderate intensities of NIR excitation below 10 W cm−2 and induce generation of radicals and photopolymerization in situ. Near infrared-activated polymerization process, both at the millimeter and sub-micron scales, was investigated. Polymeric macro- and microstructures were fabricated by means of near infrared laser scanning photolithography in the volume of liquid photocurable compositions with focused laser light at 975 nm wavelength. Examination of the polymerization process in the vicinity of the nanoparticles shows strong differences in the rate of polymer shell growth on flat and edge nanoparticle sides. This phenomenon mainly defines the resolution of the demonstrated near infrared - ultraviolet 3D printing technology at the micrometer scale level.

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Citations by journals

	1 2 3 4 5
European Polymer Journal	European Polymer Journal, 5, 7.14% European Polymer Journal 5 publications, 7.14%
Polymers	Polymers, 3, 4.29% Polymers 3 publications, 4.29%
Journal of the American Chemical Society	Journal of the American Chemical Society, 3, 4.29% Journal of the American Chemical Society 3 publications, 4.29%
Molecules	Molecules, 2, 2.86% Molecules 2 publications, 2.86%
Science China Chemistry	Science China Chemistry, 2, 2.86% Science China Chemistry 2 publications, 2.86%
Advanced Functional Materials	Advanced Functional Materials, 2, 2.86% Advanced Functional Materials 2 publications, 2.86%
Progress in Organic Coatings	Progress in Organic Coatings, 2, 2.86% Progress in Organic Coatings 2 publications, 2.86%
ChemPhotoChem	ChemPhotoChem, 2, 2.86% ChemPhotoChem 2 publications, 2.86%
Polymer Chemistry	Polymer Chemistry, 2, 2.86% Polymer Chemistry 2 publications, 2.86%
Optical Properties of Metal Oxide Nanostructures	Optical Properties of Metal Oxide Nanostructures, 2, 2.86% Optical Properties of Metal Oxide Nanostructures 2 publications, 2.86%
Photonics	Photonics, 1, 1.43% Photonics 1 publication, 1.43%
Nature	Nature, 1, 1.43% Nature 1 publication, 1.43%
Nature Photonics	Nature Photonics, 1, 1.43% Nature Photonics 1 publication, 1.43%
Scientific Reports	Scientific Reports, 1, 1.43% Scientific Reports 1 publication, 1.43%
Nano Research	Nano Research, 1, 1.43% Nano Research 1 publication, 1.43%
Chemical Physics Letters	Chemical Physics Letters, 1, 1.43% Chemical Physics Letters 1 publication, 1.43%
Journal of Photochemistry and Photobiology C: Photochemistry Reviews	Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 1, 1.43% Journal of Photochemistry and Photobiology C: Photochemistry Reviews 1 publication, 1.43%
Nano-Structures and Nano-Objects	Nano-Structures and Nano-Objects, 1, 1.43% Nano-Structures and Nano-Objects 1 publication, 1.43%
Journal of Luminescence	Journal of Luminescence, 1, 1.43% Journal of Luminescence 1 publication, 1.43%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 1.43% Journal of Alloys and Compounds 1 publication, 1.43%
Advanced Optical Materials	Advanced Optical Materials, 1, 1.43% Advanced Optical Materials 1 publication, 1.43%
Photochemistry and Photobiology	Photochemistry and Photobiology, 1, 1.43% Photochemistry and Photobiology 1 publication, 1.43%
Advanced Science	Advanced Science, 1, 1.43% Advanced Science 1 publication, 1.43%
Chemical Record	Chemical Record, 1, 1.43% Chemical Record 1 publication, 1.43%
ChemPhysChem	ChemPhysChem, 1, 1.43% ChemPhysChem 1 publication, 1.43%
Macromolecular Rapid Communications	Macromolecular Rapid Communications, 1, 1.43% Macromolecular Rapid Communications 1 publication, 1.43%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 1.43% ACS applied materials & interfaces 1 publication, 1.43%
ACS Applied Polymer Materials	ACS Applied Polymer Materials, 1, 1.43% ACS Applied Polymer Materials 1 publication, 1.43%
Nanophotonics	Nanophotonics, 1, 1.43% Nanophotonics 1 publication, 1.43%

	1 2 3 4 5

Citations by publishers

	2 4 6 8 10 12 14 16 18
Elsevier	Elsevier, 17, 24.29% Elsevier 17 publications, 24.29%
Wiley	Wiley, 11, 15.71% Wiley 11 publications, 15.71%
Springer Nature	Springer Nature, 10, 14.29% Springer Nature 10 publications, 14.29%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 8, 11.43% Multidisciplinary Digital Publishing Institute (MDPI) 8 publications, 11.43%
American Chemical Society (ACS)	American Chemical Society (ACS), 6, 8.57% American Chemical Society (ACS) 6 publications, 8.57%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 2.86% Royal Society of Chemistry (RSC) 2 publications, 2.86%
Walter de Gruyter	Walter de Gruyter, 1, 1.43% Walter de Gruyter 1 publication, 1.43%
Pleiades Publishing	Pleiades Publishing, 1, 1.43% Pleiades Publishing 1 publication, 1.43%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 1.43% American Association for the Advancement of Science (AAAS) 1 publication, 1.43%
Hindawi Limited	Hindawi Limited, 1, 1.43% Hindawi Limited 1 publication, 1.43%
Taylor & Francis	Taylor & Francis, 1, 1.43% Taylor & Francis 1 publication, 1.43%
Sechenov University	Sechenov University, 1, 1.43% Sechenov University 1 publication, 1.43%
Technosphera JSC	Technosphera JSC, 1, 1.43% Technosphera JSC 1 publication, 1.43%
Cambridge University Press	Cambridge University Press, 1, 1.43% Cambridge University Press 1 publication, 1.43%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.43% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.43%
	2 4 6 8 10 12 14 16 18

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Rocheva V. V. et al. High-resolution 3D photopolymerization assisted by upconversion nanoparticles for rapid prototyping applications // Scientific Reports. 2018. Vol. 8. No. 1. 3663

GOST all authors (up to 50) Copy

Rocheva V. V., Koroleva A. V., Savelyev A., Khaydukov K. V., Generalova A. N., Nechaev A. V., Guller A., Semchishen V. A., Chichkov B. N., Khaydukov E. V. High-resolution 3D photopolymerization assisted by upconversion nanoparticles for rapid prototyping applications // Scientific Reports. 2018. Vol. 8. No. 1. 3663

RIS |

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RIS Copy

TY - JOUR

DO - 10.1038/s41598-018-21793-0

UR - https://doi.org/10.1038%2Fs41598-018-21793-0

TI - High-resolution 3D photopolymerization assisted by upconversion nanoparticles for rapid prototyping applications

T2 - Scientific Reports

AU - Rocheva, Vasilina V

AU - Koroleva, Anastasia V

AU - Savelyev, A.G.

AU - Khaydukov, Kirill V.

AU - Generalova, Alla N

AU - Nechaev, Andrey V.

AU - Guller, Anna

AU - Semchishen, Vladimir A

AU - Chichkov, Boris N.

AU - Khaydukov, Evgeny V.

PY - 2018

DA - 2018/02/26 00:00:00

PB - Springer Nature

IS - 1

VL - 8

SN - 2045-2322

ER -

BibTex

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BibTex Copy

@article{2018_Rocheva,

author = {Vasilina V Rocheva and Anastasia V Koroleva and A.G. Savelyev and Kirill V. Khaydukov and Alla N Generalova and Andrey V. Nechaev and Anna Guller and Vladimir A Semchishen and Boris N. Chichkov and Evgeny V. Khaydukov},

title = {High-resolution 3D photopolymerization assisted by upconversion nanoparticles for rapid prototyping applications},

journal = {Scientific Reports},

year = {2018},

volume = {8},

publisher = {Springer Nature},

month = {feb},

url = {https://doi.org/10.1038%2Fs41598-018-21793-0},

number = {1},

doi = {10.1038/s41598-018-21793-0}

}

Found error?

Publisher

Springer Nature

Journal

Scientific Reports

Quartile SCImago

Quartile WOS

Impact factor

4.6

ISSN

20452322 (Print)

Labs

MPSU Youth Laboratory of Biophotonics and Nanoengineering