volume 28 issue 3 pages 35401

The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles.

S. Alyatkin 1
Kirill Khaydukov 2
A V Nechaev 2
Oleg Lebedev 3
Yu.G Vainer 4, 5
Vladimir A. Semchishen 2
Publication typeJournal Article
Publication date2016-12-08
scimago Q2
wos Q2
SJR0.597
CiteScore6.2
Impact factor2.8
ISSN09574484, 13616528
General Chemistry
General Materials Science
Electrical and Electronic Engineering
Mechanical Engineering
Bioengineering
Mechanics of Materials
Abstract
The mechanism of upconversion at the nanoscale is still under discussion. In this paper, we report on the experimental results of anti-Stokes luminescence kinetics in the upconversion nanoparticles of β-NaYF4: 20%Yb3+; 0.6%Tm3+. The parameters of the luminescence kinetics were found to be unambiguously dependent on the number of excitation quanta n, which are necessary for certain transitions between the energy states of thulium ions. The observed correlation has been explained by means of the long-lasting energy migration between the ytterbium ions. The spread in time between the luminescent maxima of the corresponding thulium transitions not only shows the nonlinear character of upconversion, but also reveals the time scale of energy migration as well. From these, we derive that the conventional Förster formalism applied to the estimation of energy transfer efficiency in UCNP-fluorophore pairs can provide misleading results.
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GOST Copy
Alyatkin S. et al. The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles. // Nanotechnology. 2016. Vol. 28. No. 3. p. 35401.
GOST all authors (up to 50) Copy
Alyatkin S., Asharchuk I., Khaydukov K., Nechaev A. V., Lebedev O., Vainer Y., Semchishen V. A., Khaydukov E. V. The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles. // Nanotechnology. 2016. Vol. 28. No. 3. p. 35401.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1088/1361-6528/28/3/035401
UR - https://doi.org/10.1088/1361-6528/28/3/035401
TI - The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles.
T2 - Nanotechnology
AU - Alyatkin, S.
AU - Asharchuk, Ilya
AU - Khaydukov, Kirill
AU - Nechaev, A V
AU - Lebedev, Oleg
AU - Vainer, Yu.G
AU - Semchishen, Vladimir A.
AU - Khaydukov, Evgeny V.
PY - 2016
DA - 2016/12/08
PB - IOP Publishing
SP - 35401
IS - 3
VL - 28
PMID - 27928995
SN - 0957-4484
SN - 1361-6528
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Alyatkin,
author = {S. Alyatkin and Ilya Asharchuk and Kirill Khaydukov and A V Nechaev and Oleg Lebedev and Yu.G Vainer and Vladimir A. Semchishen and Evgeny V. Khaydukov},
title = {The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles.},
journal = {Nanotechnology},
year = {2016},
volume = {28},
publisher = {IOP Publishing},
month = {dec},
url = {https://doi.org/10.1088/1361-6528/28/3/035401},
number = {3},
pages = {35401},
doi = {10.1088/1361-6528/28/3/035401}
}
MLA
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MLA Copy
Alyatkin, S., et al. “The influence of energy migration on luminescence kinetics parameters in upconversion nanoparticles..” Nanotechnology, vol. 28, no. 3, Dec. 2016, p. 35401. https://doi.org/10.1088/1361-6528/28/3/035401.