Dalton Transactions, volume 49, issue 43, pages 15175-15179

A new heterometallic pivalate {Fe8Cd} complex as an example of unusual “ferric wheel” molecular self-assembly

Irina A Lutsenko 1
, 
Mikhail A Kiskin 1
, 
Konstantin A. Lyssenko 2
, 
Ekaterina M Zueva 3, 4
, 
Nikolay N. Efimov 1
, 
E Ugolkova 1
, 
Yurii V Maksimov 5
, 
Vladimir K Imshennik 5
, 
Maria M Petrova 3
, 
Aleksey A Sidorov 1
, 
Igor L. Eremenko 1, 2
Show full list: 11 authors
1
 
2
 
3
 
4
 
5
 
Publication type: Journal Article
Publication date: 2020-10-07
scimago Q1
SJR: 0.697
CiteScore: 6.6
Impact factor: 3.5
ISSN: 14779226, 14779234
DOI:  10.1039/D0DT03142A
PubMed ID:  33089861
Inorganic Chemistry
Abstract

The interaction of the pivalate complexes of iron(iii), [Fe3O(Piv)6(H2O)3]·HPiv, and cadmium(ii), [Cd(Piv)2], in Et2O resulted in one more type of “ferric wheel” family complex, namely [Fe8(Piv)16{Cd(Piv)2}(μ-OH)8]·Et2O (1).

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