Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles
Ekaterina N Tarakanova
1, 2, 3, 4, 5, 6, 7
,
Pavel A Tarakanov
2, 7, 8, 9, 10, 11, 12
,
Anton O Simakov
2
,
Taniyuki Furuyama
13, 14, 15, 16, 17
,
Nagao Kobayashi
17, 18, 19, 20, 21
,
Dmitry V Konev
8, 22
,
Olga A Goncharova
8
,
Stanislav Trashin
2, 23
,
Stanislav A. Trashin
7, 9, 10, 11, 24
,
Karolien De Wael
23, 24, 25, 26, 27, 28
,
Ilya V Sulimenkov
9, 10, 11, 29, 30
,
Vasily V Filatov
29
,
Viatcheslav I Kozlovskiy
9, 10, 11, 30
,
Larisa G. Tomilova
2, 7, 9, 10, 11, 25, 31
,
Pavel A. Stuzhin
1, 3, 4, 5, 6
,
Victor E. Pushkarev
2, 7, 9, 10, 11
3
Research Institute of Macroheterocycles
5
RF-153000 Ivanovo
|
6
Russia
|
9
RUSSIAN ACADEMY OF SCIENCES
10
Chernogolovka 142432
|
11
RUSSIAN FEDERATION
|
14
Graduate school of Natural Science and Technology
15
KanazaWa University
16
Kakuma-Machi
17
JAPAN
|
19
Faculty of Textile Science and Technology
21
Tokida
24
AXES Research Group
25
DEPARTMENT OF CHEMISTRY
27
2020 Antwerpen
28
BELGIUM
|
Publication type: Journal Article
Publication date: 2021-04-01
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
33876177
Inorganic Chemistry
Abstract
Reaction of (2,3,9,10,16,17,23,24-octabutylphthalocyaninato)lanthanide(III) acetylacetonates (BuPcLn(acac), 1a–c, Ln = Lu (a), Eu (b), La (c)) with a tetrakis(5,7-bis(4-tert-butylphenyl)-6H-1,4-diazepino)[2,3-b,g,l,q]porphyrazine ligand (tBuPhDzPzH2, 2) produced sandwich compounds (tBuPhDzPz)Ln(BuPc) (3a–c), which represent the first heteroleptic double-deckers incorporating both Pc and DzPz decks. A combination of high-resolution mass spectrometry, UV–Vis/NIR, MCD, and 1H NMR spectroscopy, and square-wave voltammetry provided unambiguous characterization of target complexes 3 indicating that their spectral and electrochemical properties are generally intermediate with respect to their homoleptic relatives. Based on the data of solution-state 1H–1H NMR (COSY, NOESY) correlation spectroscopy supported by DFT calculations, a dimerization tendency of compounds 3 proportional to the Ln(III) ion size was found. The spectroelectrochemical study of 3 and the corresponding homoleptic double-deckers revealed a pronounced tendency to aggregation of the one-electron oxidized forms of DzPz-containing double-decker complexes compared to homoleptic Pc2Ln compounds.
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Total citations:
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Tarakanova E. N. et al. Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles // Dalton Transactions. 2021. Vol. 50. No. 18. pp. 6245-6255.
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Tarakanova E. N. et al. Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles // Dalton Transactions. 2021. Vol. 50. No. 18. pp. 6245-6255.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d1dt00088h
UR - https://xlink.rsc.org/?DOI=D1DT00088H
TI - Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles
T2 - Dalton Transactions
AU - Tarakanova, Ekaterina N
AU - Tarakanov, Pavel A
AU - Simakov, Anton O
AU - Furuyama, Taniyuki
AU - Kobayashi, Nagao
AU - Konev, Dmitry V
AU - Goncharova, Olga A
AU - Trashin, Stanislav
AU - Trashin, Stanislav A.
AU - De Wael, Karolien
AU - Sulimenkov, Ilya V
AU - Filatov, Vasily V
AU - Kozlovskiy, Viacheslav
AU - Kozlovskiy, Viatcheslav I
AU - Tomilova, Larisa G.
AU - Stuzhin, Pavel A.
AU - E. Pushkarev, Victor
PY - 2021
DA - 2021/04/01
PB - Royal Society of Chemistry (RSC)
SP - 6245-6255
IS - 18
VL - 50
PMID - 33876177
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2021_Tarakanova,
author = {Ekaterina N Tarakanova and Pavel A Tarakanov and Anton O Simakov and Taniyuki Furuyama and Nagao Kobayashi and Dmitry V Konev and Olga A Goncharova and Stanislav Trashin and Stanislav A. Trashin and Karolien De Wael and Ilya V Sulimenkov and Vasily V Filatov and Viacheslav Kozlovskiy and Viatcheslav I Kozlovskiy and Larisa G. Tomilova and Pavel A. Stuzhin and Victor E. Pushkarev and others},
title = {Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=D1DT00088H},
number = {18},
pages = {6245--6255},
doi = {10.1039/d1dt00088h}
}
Cite this
MLA
Copy
Tarakanova, Ekaterina N., et al. “Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles.” Dalton Transactions, vol. 50, no. 18, Apr. 2021, pp. 6245-6255. https://xlink.rsc.org/?DOI=D1DT00088H.
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