Chemical Communications, issue 23, pages 2510-2512

A key step in the formation of acrylic acid from CO2and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex

Publication typeJournal Article
Publication date2006-06-07
scimago Q1
SJR1.133
CiteScore8.6
Impact factor4.3
ISSN13597345, 1364548X
PubMed ID:  16758032
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.
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