Chemical Communications, issue 23, pages 2510-2512
A key step in the formation of acrylic acid from CO2and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex
Reinald Fischer
1
,
Jens Langer
1
,
Astrid Malassa
1
,
Dirk Walther
1
,
Helmar Görls
1
,
Publication type: Journal Article
Publication date: 2006-06-07
Journal:
Chemical Communications
scimago Q1
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
DOI:
10.1039/b603540j
PubMed ID:
16758032
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.
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