Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy.
Publication type: Journal Article
Publication date: 2014-07-17
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
25056429
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The first direct mechanochemical transition-metal-mediated activation of strong phenyl C-H bonds is reported. The mechanochemical procedure, resulting in cyclopalladated complexes, is quantitative and significantly faster than solution synthesis and allows highly regioselective activation of two C-H bonds by palladium(II) acetate in asymmetrically substituted azobenzene. Milling is monitored by in situ solid-state Raman spectroscopy which in combination with quantum-chemical calculations enabled characterization of involved reaction species, direct insight into the dynamics and reaction pathways, as well as the optimization of a milling process.
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126
Total citations:
126
Citations from 2025:
12
(9.52%)
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Juribašić M. et al. Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy. // Chemical Communications. 2014. Vol. 50. No. 71. pp. 10287-10290.
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Juribašić M., Užarević K., Gracin D., Ćurić M. Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy. // Chemical Communications. 2014. Vol. 50. No. 71. pp. 10287-10290.
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RIS
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TY - JOUR
DO - 10.1039/C4CC04423A
UR - https://doi.org/10.1039/C4CC04423A
TI - Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy.
T2 - Chemical Communications
AU - Juribašić, Marina
AU - Užarević, K.
AU - Gracin, Davor
AU - Ćurić, Manda
PY - 2014
DA - 2014/07/17
PB - Royal Society of Chemistry (RSC)
SP - 10287-10290
IS - 71
VL - 50
PMID - 25056429
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2014_Juribašić,
author = {Marina Juribašić and K. Užarević and Davor Gracin and Manda Ćurić},
title = {Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy.},
journal = {Chemical Communications},
year = {2014},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://doi.org/10.1039/C4CC04423A},
number = {71},
pages = {10287--10290},
doi = {10.1039/C4CC04423A}
}
Cite this
MLA
Copy
Juribašić, Marina, et al. “Mechanochemical C-H bond activation: rapid and regioselective double cyclopalladation monitored by in situ Raman spectroscopy..” Chemical Communications, vol. 50, no. 71, Jul. 2014, pp. 10287-10290. https://doi.org/10.1039/C4CC04423A.
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