Royal Society of Chemistry (RSC)
Organic and Biomolecular Chemistry
,  volume 16 ,  issue 41 ,  pages 7693-7701

Formal reductive addition of acetonitrile to aldehydes and ketones.

Publication type: Journal Article
Publication date: 2018-09-28
Royal Society of Chemistry (RSC)
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
DOI:  10.1039/C8OB01992D
PubMed ID:  30288533
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An efficient and highly productive rhodium-catalyzed method for the synthesis of nitriles employing aldehydes or ketones, methyl cyanoacetate, water and carbon monoxide as starting materials has been developed. Simple rhodium chloride without any ligands can be used. The fine tuning of the substrate can lead to the activity higher than 5000 TON.
Found 
Found 
1 citation
Rubtsov Aleksandr
🥼 🤝
PhD in Chemistry, associate professor
76 publications,  1 034 citations
h-index: 20
Perm State National Research University
Perm State National Research University
Research interests
Antibiotics
Asymmetric synthesis
Green chemistry
Organic Chemistry
Organic synthesis
Organometallic Chemistry
1 citation
Chusov Denis
DSc in Chemistry, professor
100 publications,  2 414 citations,  36 reviews
h-index: 25
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Catalysis
Medicinal Chemistry
Organic Chemistry
Total synthesis
1 citation
Smirnov Ivan
5 publications,  9 citations
h-index: 3
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
National Research University Higher School of Economics
National Research University Higher School of Economics
Research interests
Catalysis
Data analysis
Machine learning
Organic Chemistry
Organometallic Chemistry

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GOST Copy
Muratov K. et al. Formal reductive addition of acetonitrile to aldehydes and ketones. // Organic and Biomolecular Chemistry. 2018. Vol. 16. No. 41. pp. 7693-7701.
GOST all authors (up to 50) Copy
Muratov K., Kuchuk E., Vellalath S., Afanasyev O. I., Moskovets A. P., Denisov G. L., Chusov D. Formal reductive addition of acetonitrile to aldehydes and ketones. // Organic and Biomolecular Chemistry. 2018. Vol. 16. No. 41. pp. 7693-7701.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/C8OB01992D
UR - https://xlink.rsc.org/?DOI=C8OB01992D
TI - Formal reductive addition of acetonitrile to aldehydes and ketones.
T2 - Organic and Biomolecular Chemistry
AU - Muratov, Karim
AU - Kuchuk, Ekaterina
AU - Vellalath, Sreekumar
AU - Afanasyev, Oleg I
AU - Moskovets, Alexei P
AU - Denisov, Gleb L
AU - Chusov, Denis
PY - 2018
DA - 2018/09/28
PB - Royal Society of Chemistry (RSC)
SP - 7693-7701
IS - 41
VL - 16
PMID - 30288533
SN - 1477-0520
SN - 1477-0539
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Muratov,
author = {Karim Muratov and Ekaterina Kuchuk and Sreekumar Vellalath and Oleg I Afanasyev and Alexei P Moskovets and Gleb L Denisov and Denis Chusov},
title = {Formal reductive addition of acetonitrile to aldehydes and ketones.},
journal = {Organic and Biomolecular Chemistry},
year = {2018},
volume = {16},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=C8OB01992D},
number = {41},
pages = {7693--7701},
doi = {10.1039/C8OB01992D}
}
MLA
Cite this
MLA Copy
Muratov, Karim, et al. “Formal reductive addition of acetonitrile to aldehydes and ketones..” Organic and Biomolecular Chemistry, vol. 16, no. 41, Sep. 2018, pp. 7693-7701. https://xlink.rsc.org/?DOI=C8OB01992D.