Oxidative addition of verdazyl halogenides to Pd(PPh3)4
Pavel Petunin
1, 2, 3, 4
,
Darya E Votkina
1, 2, 3
,
Marina E. Trusova
1, 2, 3
,
Tatyana V. Rybalova
3, 5, 6, 7, 8
,
Evgeny V Amosov
3, 5, 6, 7, 8
,
Mikhail N. Uvarov
3, 6, 8, 9, 10
,
Pavel S. Postnikov
1, 2, 3, 11, 12
,
Maxim S. Kazantsev
3, 5, 6, 7, 8
,
Evgeny A. Mostovich
3, 8, 9
2
Tomsk 634050
|
3
Russia
|
6
Siberian Branch
7
RUSSIAN ACADEMY OF SCIENCES
8
Novosibirsk 630090
|
12
Prague 16628
|
Publication type: Journal Article
Publication date: 2019-09-02
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
Direct oxidative addition of verdazyl halogenides to Pd(0) was studied and the role of this step in the Pd-catalyzed cross-coupling reactions was evaluated. A number of bis(triphenylphosphine)[verdazyl]palladium(II) iodide species were synthesized in yields of 89 to 92% and were shown to be persistent under ambient conditions. High synthetic potential of Pd-verdazyls was demonstrated by their efficiency and reactivity in the Sonogashira coupling reaction. These derivatives significantly expand the modern synthetic tools for development of spin-labeled materials and polyradical systems with desired functionalities.
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Total citations:
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Citations from 2024:
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(23.07%)
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GOST
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Petunin P. et al. Oxidative addition of verdazyl halogenides to Pd(PPh3)4 // New Journal of Chemistry. 2019. Vol. 43. No. 38. pp. 15293-15301.
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Petunin P., Votkina D. E., E. Trusova M., Rybalova T. V., Amosov E. V., Uvarov M. N., Postnikov P. S., Kazantsev M. S., Mostovich E. A. Oxidative addition of verdazyl halogenides to Pd(PPh3)4 // New Journal of Chemistry. 2019. Vol. 43. No. 38. pp. 15293-15301.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C9NJ03361K
UR - https://xlink.rsc.org/?DOI=C9NJ03361K
TI - Oxidative addition of verdazyl halogenides to Pd(PPh3)4
T2 - New Journal of Chemistry
AU - Petunin, Pavel
AU - Votkina, Darya E
AU - E. Trusova, Marina
AU - Rybalova, Tatyana V.
AU - Amosov, Evgeny V
AU - Uvarov, Mikhail N.
AU - Postnikov, Pavel S.
AU - Kazantsev, Maxim S.
AU - Mostovich, Evgeny A.
PY - 2019
DA - 2019/09/02
PB - Royal Society of Chemistry (RSC)
SP - 15293-15301
IS - 38
VL - 43
SN - 1144-0546
SN - 1369-9261
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Petunin,
author = {Pavel Petunin and Darya E Votkina and Marina E. Trusova and Tatyana V. Rybalova and Evgeny V Amosov and Mikhail N. Uvarov and Pavel S. Postnikov and Maxim S. Kazantsev and Evgeny A. Mostovich},
title = {Oxidative addition of verdazyl halogenides to Pd(PPh3)4},
journal = {New Journal of Chemistry},
year = {2019},
volume = {43},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=C9NJ03361K},
number = {38},
pages = {15293--15301},
doi = {10.1039/C9NJ03361K}
}
Cite this
MLA
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Petunin, Pavel, et al. “Oxidative addition of verdazyl halogenides to Pd(PPh3)4.” New Journal of Chemistry, vol. 43, no. 38, Sep. 2019, pp. 15293-15301. https://xlink.rsc.org/?DOI=C9NJ03361K.