Open Access
A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes
Mikhail O Zubkov
1, 2, 3, 4, 5, 6, 7
,
Mikhail D Kosobokov
1, 3, 4, 5, 6
,
Vitalij V Levin
1, 3, 4, 5, 6
,
Vladimir A. Kokorekin
1, 8
,
Alexander Korlyukov
4, 5, 6, 9, 10, 11, 12
,
Jinbo Hu
13, 14, 15, 16, 17, 18
,
Alexander D Dilman
1, 3, 4, 5, 6
4
RUSSIAN ACADEMY OF SCIENCES
5
119991 Moscow
6
Russia
|
7
Higher Chemical College
8
10
14
Key Laboratory of Organofluorine Chemistry
15
Center for Excellence in Molecular Synthesis
18
Chinese Academy of sciences
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q1
wos Q1
SJR: 2.138
CiteScore: 12.6
Impact factor: 7.4
ISSN: 20416520, 20416539
PubMed ID:
34123046
General Chemistry
Abstract
A 4-tetrafluoropyridinylthio group was suggested as a new photoredox-active moiety. The group can be directly installed on difluorostyrenes in a single step by the thiolene click reaction. It proceeds upon visible light catalysis with 9-phenylacridine providing various difluorinated sulfides as radical precursors. Single electron reduction of the C–S bond with the formation of fluoroalkyl radicals is enabled by the electron-poor azine ring. The intermediate difluorinated sulfides were involved in a series of photoredox reactions with silyl enol ethers, alkenes, nitrones and an alkenyl trifluoroborate.
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99
Total citations:
99
Citations from 2025:
15
(15.15%)
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GOST
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Zubkov M. O. et al. A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes // Chemical Science. 2020. Vol. 11. No. 3. pp. 737-741.
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Zubkov M. O., Kosobokov M. D., Levin V. V., Kokorekin V. A., Korlyukov A., Hu J., Dilman A. D. A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes // Chemical Science. 2020. Vol. 11. No. 3. pp. 737-741.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/C9SC04643G
UR - https://xlink.rsc.org/?DOI=C9SC04643G
TI - A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes
T2 - Chemical Science
AU - Zubkov, Mikhail O
AU - Kosobokov, Mikhail D
AU - Levin, Vitalij V
AU - Kokorekin, Vladimir A.
AU - Korlyukov, Alexander
AU - Hu, Jinbo
AU - Dilman, Alexander D
PY - 2020
DA - 2020/01/01
PB - Royal Society of Chemistry (RSC)
SP - 737-741
IS - 3
VL - 11
PMID - 34123046
SN - 2041-6520
SN - 2041-6539
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Zubkov,
author = {Mikhail O Zubkov and Mikhail D Kosobokov and Vitalij V Levin and Vladimir A. Kokorekin and Alexander Korlyukov and Jinbo Hu and Alexander D Dilman},
title = {A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes},
journal = {Chemical Science},
year = {2020},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9SC04643G},
number = {3},
pages = {737--741},
doi = {10.1039/C9SC04643G}
}
Cite this
MLA
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Zubkov, Mikhail O., et al. “A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes.” Chemical Science, vol. 11, no. 3, Jan. 2020, pp. 737-741. https://xlink.rsc.org/?DOI=C9SC04643G.