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volume 11 issue 59 pages 37540-37543

Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions

Publication typeJournal Article
Publication date2021-11-22
scimago Q1
wos Q2
SJR0.777
CiteScore7.6
Impact factor4.6
ISSN20462069
PubMed ID:  35496383
General Chemistry
General Chemical Engineering
Abstract
A mild, efficient electrochemical approach to the site-selective direct C-H amidation of benzene and its derivatives with acetonitrile and benzonitrile has been developed. It has been shown that joint electrochemical oxidation of various arenes in the presence of a copper salt as a catalyst and nitriles leads to the formation of N-phenylacetamide from benzene and N-benzylacetamides from benzyl derivatives (up to 78% yield). A favorable feature of the process is mild conditions (room temperature, ambient pressure, no strong oxidants) that meet the criteria of green chemistry.
Found 
Found 

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GOST |
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GOST Copy
Strekalova S. et al. Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions // RSC Advances. 2021. Vol. 11. No. 59. pp. 37540-37543.
GOST all authors (up to 50) Copy
Strekalova S., Kononov A., Rizvanov I., Budnikova Y. H. Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions // RSC Advances. 2021. Vol. 11. No. 59. pp. 37540-37543.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/d1ra07650g
UR - https://xlink.rsc.org/?DOI=D1RA07650G
TI - Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions
T2 - RSC Advances
AU - Strekalova, Sofia
AU - Kononov, Alexander
AU - Rizvanov, Ildar
AU - Budnikova, Yulia H.
PY - 2021
DA - 2021/11/22
PB - Royal Society of Chemistry (RSC)
SP - 37540-37543
IS - 59
VL - 11
PMID - 35496383
SN - 2046-2069
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Strekalova,
author = {Sofia Strekalova and Alexander Kononov and Ildar Rizvanov and Yulia H. Budnikova},
title = {Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions},
journal = {RSC Advances},
year = {2021},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {nov},
url = {https://xlink.rsc.org/?DOI=D1RA07650G},
number = {59},
pages = {37540--37543},
doi = {10.1039/d1ra07650g}
}
MLA
Cite this
MLA Copy
Strekalova, Sofia, et al. “Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions.” RSC Advances, vol. 11, no. 59, Nov. 2021, pp. 37540-37543. https://xlink.rsc.org/?DOI=D1RA07650G.