Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach
Evgeniya A Trifonova
1, 2
,
Nikita M Ankudinov
1, 2
,
Denis Chusov
1, 2
,
Yulia V. Nelyubina
1, 2
,
Dmitry S Perekalin
1, 2
Publication type: Journal Article
Publication date: 2022-05-12
scimago Q1
wos Q2
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
35593764
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
Asymmetric cyclopropanation of alkenes by aryldiazoacetates was achieved using the readily-available racemic (diene)rhodium complex in combination with the chiral oxazoline-phenol ligand, which acts as the chiral poison and selectively inhibits one of the enantiomers of the catalyst. This approach eliminates a common problematic step of the synthesis of chiral catalysts.
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Total citations:
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Citations from 2024:
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Trifonova E. A. et al. Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach // Chemical Communications. 2022. Vol. 58. No. 47. pp. 6709-6712.
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Trifonova E. A., Ankudinov N. M., Chusov D., Nelyubina Y. V., Perekalin D. S. Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach // Chemical Communications. 2022. Vol. 58. No. 47. pp. 6709-6712.
Cite this
RIS
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TY - JOUR
DO - 10.1039/D2CC01648F
UR - https://xlink.rsc.org/?DOI=D2CC01648F
TI - Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach
T2 - Chemical Communications
AU - Trifonova, Evgeniya A
AU - Ankudinov, Nikita M
AU - Chusov, Denis
AU - Nelyubina, Yulia V.
AU - Perekalin, Dmitry S
PY - 2022
DA - 2022/05/12
PB - Royal Society of Chemistry (RSC)
SP - 6709-6712
IS - 47
VL - 58
PMID - 35593764
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (up to 50 authors)
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@article{2022_Trifonova,
author = {Evgeniya A Trifonova and Nikita M Ankudinov and Denis Chusov and Yulia V. Nelyubina and Dmitry S Perekalin},
title = {Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach},
journal = {Chemical Communications},
year = {2022},
volume = {58},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=D2CC01648F},
number = {47},
pages = {6709--6712},
doi = {10.1039/D2CC01648F}
}
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MLA
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Trifonova, Evgeniya A., et al. “Asymmetric cyclopropanation of electron-rich alkenes by the racemic diene rhodium catalyst: the chiral poisoning approach.” Chemical Communications, vol. 58, no. 47, May. 2022, pp. 6709-6712. https://xlink.rsc.org/?DOI=D2CC01648F.