Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra
Publication type: Journal Article
Publication date: 2009-06-29
scimago Q2
wos Q2
SJR: 0.698
CiteScore: 5.3
Impact factor: 2.9
ISSN: 14639076, 14639084
DOI:
10.1039/b905524j
PubMed ID:
19639144
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Pulsed electron electron double resonance (PELDOR) is a well-established method for measuring nanometer distances between paramagnetic centres. Here, we demonstrate on three rigid and conjugated biradicals how the presence of an exchange coupling constant J and its distribtion DeltaJ influences PELDOR data and its analysis. In principle two combinations of J and D fulfill the experimental data in each case. The correct one, including the sign of J, can be determined via simulations in case the two halves of the Pake pattern are separated enough.
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46
Total citations:
46
Citations from 2025:
1
(2.17%)
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MLA
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GOST
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Margraf D. et al. Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra // Physical Chemistry Chemical Physics. 2009. Vol. 11. No. 31. p. 6708.
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Margraf D., Cekan P., Prisner T. F., Sigurdsson S. T., Schiemann O. Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra // Physical Chemistry Chemical Physics. 2009. Vol. 11. No. 31. p. 6708.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/b905524j
UR - https://doi.org/10.1039/b905524j
TI - Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra
T2 - Physical Chemistry Chemical Physics
AU - Margraf, D
AU - Cekan, P
AU - Prisner, Thomas F.
AU - Sigurdsson, Snorri Th.
AU - Schiemann, Olav
PY - 2009
DA - 2009/06/29
PB - Royal Society of Chemistry (RSC)
SP - 6708
IS - 31
VL - 11
PMID - 19639144
SN - 1463-9076
SN - 1463-9084
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Margraf,
author = {D Margraf and P Cekan and Thomas F. Prisner and Snorri Th. Sigurdsson and Olav Schiemann},
title = {Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra},
journal = {Physical Chemistry Chemical Physics},
year = {2009},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://doi.org/10.1039/b905524j},
number = {31},
pages = {6708},
doi = {10.1039/b905524j}
}
Cite this
MLA
Copy
Margraf, D., et al. “Ferro- and antiferromagnetic exchange coupling constants in PELDOR spectra.” Physical Chemistry Chemical Physics, vol. 11, no. 31, Jun. 2009, p. 6708. https://doi.org/10.1039/b905524j.
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