volume 40 issue 27 pages 7165-7171

Novel approaches to model-free analysis of lanthanide-induced shifts, targeted to the investigation of contact term behavior

Publication typeJournal Article
Publication date2011-06-10
scimago Q2
wos Q1
SJR0.653
CiteScore6.0
Impact factor3.3
ISSN14779226, 14779234
PubMed ID:  21666892
Inorganic Chemistry
Abstract
Three novel equations were proposed to perform graphical model-free analysis of lanthanide-induced shifts in NMR spectra of axially symmetrical complexes within Bleaney's T(-2) expansion. Application and efficiency of these newly developed approaches were demonstrated on the example of heteroleptic triple-decker crown-phthalocyaninates (Pc)M[(15C5)(4)Pc]M(Pc), where (15C5)--15-crown-5, (Pc(2-))--phthalocyaninato-dianion, M = Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, Yb and Y as diamagnetic reference. By construction of these equations, the proposed analytical techniques are more sensitive to variations of hyperfine coupling terms throughout lanthanide series, in comparison with previously developed approaches, becoming a valuable tool for the investigation of structural and electronic characteristics of lanthanide complexes.
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Martynov A. G. et al. Novel approaches to model-free analysis of lanthanide-induced shifts, targeted to the investigation of contact term behavior // Dalton Transactions. 2011. Vol. 40. No. 27. pp. 7165-7171.
GOST all authors (up to 50) Copy
Martynov A. G., Gorbunova Y. G., Tsivadze A. Novel approaches to model-free analysis of lanthanide-induced shifts, targeted to the investigation of contact term behavior // Dalton Transactions. 2011. Vol. 40. No. 27. pp. 7165-7171.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/c1dt10455a
UR - https://xlink.rsc.org/?DOI=c1dt10455a
TI - Novel approaches to model-free analysis of lanthanide-induced shifts, targeted to the investigation of contact term behavior
T2 - Dalton Transactions
AU - Martynov, Alexander G.
AU - Gorbunova, Yulia G.
AU - Tsivadze, Aslan
PY - 2011
DA - 2011/06/10
PB - Royal Society of Chemistry (RSC)
SP - 7165-7171
IS - 27
VL - 40
PMID - 21666892
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Martynov,
author = {Alexander G. Martynov and Yulia G. Gorbunova and Aslan Tsivadze},
title = {Novel approaches to model-free analysis of lanthanide-induced shifts, targeted to the investigation of contact term behavior},
journal = {Dalton Transactions},
year = {2011},
volume = {40},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=c1dt10455a},
number = {27},
pages = {7165--7171},
doi = {10.1039/c1dt10455a}
}
MLA
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MLA Copy
Martynov, Alexander G., et al. “Novel approaches to model-free analysis of lanthanide-induced shifts, targeted to the investigation of contact term behavior.” Dalton Transactions, vol. 40, no. 27, Jun. 2011, pp. 7165-7171. https://xlink.rsc.org/?DOI=c1dt10455a.