Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand
Jing Cui Wang
1
,
Jing-Cui Wang
1
,
Zhen Jiang Xu
1
,
Zhen Guo
2
,
Qing Hai Deng
1
,
Qing-Hai Deng
1
,
Cong Ying Zhou
2
,
Xiao-Long Wan
1
,
Chi Ming Che
1, 2
Тип публикации: Journal Article
Дата публикации: 2012-03-26
scimago Q1
wos Q2
БС1
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
22447038
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Краткое описание
The chiral iridium porphyrin [Ir((-)-D(4)-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee).
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ГОСТ
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Wang J. C. et al. Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand // Chemical Communications. 2012. Vol. 48. No. 36. p. 4299.
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Wang J. C., Wang J., Xu Z. J., Guo Z., Deng Q. H., Deng Q., Zhou C. Y., Wan X., Che C. M. Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand // Chemical Communications. 2012. Vol. 48. No. 36. p. 4299.
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TY - JOUR
DO - 10.1039/c2cc30441d
UR - https://doi.org/10.1039/c2cc30441d
TI - Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand
T2 - Chemical Communications
AU - Wang, Jing Cui
AU - Wang, Jing-Cui
AU - Xu, Zhen Jiang
AU - Guo, Zhen
AU - Deng, Qing Hai
AU - Deng, Qing-Hai
AU - Zhou, Cong Ying
AU - Wan, Xiao-Long
AU - Che, Chi Ming
PY - 2012
DA - 2012/03/26
PB - Royal Society of Chemistry (RSC)
SP - 4299
IS - 36
VL - 48
PMID - 22447038
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2012_Wang,
author = {Jing Cui Wang and Jing-Cui Wang and Zhen Jiang Xu and Zhen Guo and Qing Hai Deng and Qing-Hai Deng and Cong Ying Zhou and Xiao-Long Wan and Chi Ming Che},
title = {Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand},
journal = {Chemical Communications},
year = {2012},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039/c2cc30441d},
number = {36},
pages = {4299},
doi = {10.1039/c2cc30441d}
}
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MLA
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Wang, Jing Cui, et al. “Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand.” Chemical Communications, vol. 48, no. 36, Mar. 2012, p. 4299. https://doi.org/10.1039/c2cc30441d.
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