volume 42 issue 29 pages 10394

Metal-mediated coupling of a coordinated isocyanide and indazoles

Publication typeJournal Article
Publication date2013-06-11
scimago Q2
wos Q1
SJR0.653
CiteScore6.0
Impact factor3.3
ISSN14779226, 14779234
PubMed ID:  23784003
Inorganic Chemistry
Abstract
A reaction between equimolar amounts of cis-[PdCl2(CNCy)2] (1) and indazole (HInd, 2) or 5-methylindazole (HInd(Me), 3) proceeded in refluxing CHCl3 for ca. 6 h affording the aminocarbene species cis-[PdCl2{C(Ind)=N(H)Cy}(CNCy)] (4) or cis-[PdCl2{C(Ind(Me))=N(H)Cy}(CNCy)] (5) in good (72-83%) isolated yields. Complexes 4 and 5 were characterized by elemental analyses (C, H, N), HR ESI(+)-MS, IR, and 1D ((1)H, (13)C{(1)H}) and 2D ((1)H,(1)H-COSY, (1)H,(13)C-HMQC/(1)H,(13)C-HSQC, (1)H,(13)C-HMBC) NMR spectroscopies, and complex 4 as well by X-ray diffraction. The observed coupling represents the first example of metal-mediated integration between any isocyanide and any aromatic heterocyclic system having an HN center.
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GOST Copy
Kinzhalov M. A. et al. Metal-mediated coupling of a coordinated isocyanide and indazoles // Dalton Transactions. 2013. Vol. 42. No. 29. p. 10394.
GOST all authors (up to 50) Copy
Kinzhalov M. A., Boyarskiy V. P., Luzyanin K., Dolgushin F., Kukushkin V. Y. Metal-mediated coupling of a coordinated isocyanide and indazoles // Dalton Transactions. 2013. Vol. 42. No. 29. p. 10394.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/c3dt51335a
UR - https://xlink.rsc.org/?DOI=c3dt51335a
TI - Metal-mediated coupling of a coordinated isocyanide and indazoles
T2 - Dalton Transactions
AU - Kinzhalov, M. A.
AU - Boyarskiy, Vadim P
AU - Luzyanin, Konstantin
AU - Dolgushin, Fedor
AU - Kukushkin, Vadim Yu.
PY - 2013
DA - 2013/06/11
PB - Royal Society of Chemistry (RSC)
SP - 10394
IS - 29
VL - 42
PMID - 23784003
SN - 1477-9226
SN - 1477-9234
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Kinzhalov,
author = {M. A. Kinzhalov and Vadim P Boyarskiy and Konstantin Luzyanin and Fedor Dolgushin and Vadim Yu. Kukushkin},
title = {Metal-mediated coupling of a coordinated isocyanide and indazoles},
journal = {Dalton Transactions},
year = {2013},
volume = {42},
publisher = {Royal Society of Chemistry (RSC)},
month = {jun},
url = {https://xlink.rsc.org/?DOI=c3dt51335a},
number = {29},
pages = {10394},
doi = {10.1039/c3dt51335a}
}
MLA
Cite this
MLA Copy
Kinzhalov, M. A., et al. “Metal-mediated coupling of a coordinated isocyanide and indazoles.” Dalton Transactions, vol. 42, no. 29, Jun. 2013, p. 10394. https://xlink.rsc.org/?DOI=c3dt51335a.