Dalton Transactions

, volume 48 , issue 10 , pages 3447-3452

Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions

Alexandra A Ageshina ^{1, 2, 3, 4, 5}

Grigorii K Sterligov ^{1, 2, 3, 4, 5, 6, 7}

Sergey A Rzhevskiy ^{1, 2, 3, 4, 5, 6, 7}

Maxim A Topchiy ^{1, 2, 3, 4, 5, 6, 7}

Gleb A Chesnokov ^{1, 2, 3, 4, 5, 6, 7}

Pavel S Gribanov ^{1, 2, 3, 4, 5, 8, 9}

Elizaveta K Melnikova ^{6, 8}

Mikhail Petrovich Nechaev ^{1, 2, 3, 4, 5, 6, 7}

Andrey Asachenko ^{1, 2, 3, 4, 5, 6, 7}

M.V. Bermeshev ^{1, 2, 3, 4, 5}

Hide authors affiliations Show authors affiliations: 9 affiliations

A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninsky Prospect 29, Moscow, Russian Federation |

A.V. Topchiev Institute of Petrochemical Synthesis |

RUSSIAN ACADEMY OF SCIENCES

⁴

Moscow

⁵

RUSSIAN FEDERATION |

⁶

M.V. Lomonosov Moscow State University, Leninskie Gory 1 (3), Moscow, Russian Federation |

⁷

M.V. lomonosov Moscow State University |

⁸

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, Moscow, Russian Federation |

⁹

A.N. Nesmeyanov Institute of Organoelement Compounds |

Publication type: Journal Article

Publication date: 2019-02-13

Royal Society of Chemistry (RSC)

Dalton Transactions

scimago Q2

wos Q1

SJR: 0.653

CiteScore: 6.0

Impact factor: 3.3

ISSN: 14779226, 14779234

DOI: 10.1039/c9dt00216b

Copy DOI

PubMed ID: 30793148

Inorganic Chemistry

Abstract

A series of novel (NHC)PdCl2-PR3 complexes were synthesized and fully characterized by 1H, 13C, 31P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald–Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable N-aryl carbazoles and similar N-heterocyclic systems was described.

Found

3 citations

Bermeshev Maxim

🥼 🤝

DSc in Chemistry, associate professor, associate member of the Russian Academy of Sciences

210 publications, 2 853 citations, 43 reviews

h-index: 27

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences

Research interests

Metathesis polymerization

3 citations

Osipov Sergey

DSc in Chemistry

138 publications, 2 746 citations, 3 reviews

h-index: 29

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

2 citations

Cherkaschenko Ilyya

🥼 🤝

10 publications, 52 citations

h-index: 5

Lomonosov Moscow State University

Skolkovo Institute of Science and Technology

Research interests

Metal-ion batteries

Solid state chemistry

1 citation

Afanasyev Oleg

51 publications, 1 263 citations, 11 reviews

h-index: 13

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

1 citation

Prima Darya

🥼 🤝

PhD in Chemistry

21 publications, 409 citations

h-index: 9

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Heterocyclic compounds

Organic Chemistry

Organic synthesis

Organometallic Chemistry

Perfluorinated compounds

1 citation

Lyssenko Konstantin

🥼 🤝

DSc in Chemistry, professor

898 publications, 15 180 citations, 2 reviews

h-index: 50

Lomonosov Moscow State University

National Research University Higher School of Economics

Research interests

Supramolecular chemistry

1 citation

Eliseev O

87 publications, 728 citations, 3 reviews

h-index: 17

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Peoples' Friendship University of Russia

1 citation

Wozniak Alyona

PhD in Chemistry

38 publications, 410 citations

h-index: 11

A.V. Topchiev Institute of Petrochemical Synthesis RAS

1 citation

Tokarev Sergey

🥼

PhD in Chemistry

24 publications, 226 citations

h-index: 8

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Coordination Chemistry

1 citation

Chusov Denis

DSc in Chemistry, professor

98 publications, 2 386 citations, 35 reviews

h-index: 25

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Asymmetric metal complex catalysis

1 citation

Rodionov Aleksey

PhD in Chemistry

49 publications, 448 citations

h-index: 12

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

1 citation

Atoian Edita

2 publications, 22 citations

h-index: 1

Skolkovo Institute of Science and Technology

1 citation

Khrychikova Anna

8 publications, 79 citations

h-index: 5

A.V. Topchiev Institute of Petrochemical Synthesis RAS

Research interests

Additive polymerization

Catalysis

High molecular weight compounds

Transition metal complexes

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Ageshina A. A. et al. Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions // Dalton Transactions. 2019. Vol. 48. No. 10. pp. 3447-3452.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/c9dt00216b

UR - https://xlink.rsc.org/?DOI=C9DT00216B

TI - Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions

T2 - Dalton Transactions

AU - Ageshina, Alexandra A

AU - Sterligov, Grigorii K

AU - Rzhevskiy, Sergey A

AU - Topchiy, Maxim A

AU - Chesnokov, Gleb A

AU - Gribanov, Pavel S

AU - Melnikova, Elizaveta K

AU - Nechaev, Mikhail Petrovich

AU - Asachenko, Andrey

AU - Bermeshev, M.V.

PY - 2019

DA - 2019/02/13

PB - Royal Society of Chemistry (RSC)

SP - 3447-3452

IS - 10

VL - 48

PMID - 30793148

SN - 1477-9226

SN - 1477-9234

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2019_Ageshina,

author = {Alexandra A Ageshina and Grigorii K Sterligov and Sergey A Rzhevskiy and Maxim A Topchiy and Gleb A Chesnokov and Pavel S Gribanov and Elizaveta K Melnikova and Mikhail Petrovich Nechaev and Andrey Asachenko and M.V. Bermeshev and others},

title = {Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions},

journal = {Dalton Transactions},

year = {2019},

volume = {48},

publisher = {Royal Society of Chemistry (RSC)},

month = {feb},

url = {https://xlink.rsc.org/?DOI=C9DT00216B},

number = {10},

pages = {3447--3452},

doi = {10.1039/c9dt00216b}

}

MLA

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Ageshina, Alexandra A., et al. “Mixed er-NHC/phosphine Pd(ii) complexes and their catalytic activity in the Buchwald–Hartwig reaction under solvent-free conditions.” Dalton Transactions, vol. 48, no. 10, Feb. 2019, pp. 3447-3452. https://xlink.rsc.org/?DOI=C9DT00216B.

Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q2

wos Q1

SJR

0.653

CiteScore

6.0

Impact factor

3.3

ISSN

14779226 (Print)

14779234 (Electronic)

Labs

Laboratory of Organosilicon and Hydrocarbon Cyclic Compounds (No. 10)

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