Syngas as a synergistic reducing agent for the selective reductive amination – a mild route to bioactive amines
Evgeniya Podyacheva
1, 2
,
Alexandra I Balalaeva
1
,
Oleg I Afanasyev
1, 3
,
Sofiya A Runikhina
1
,
Olga Chusova
1, 4
,
Andrey S Kozlov
1
,
Saihu Liao
5
,
Denis Chusov
1, 2
3
Publication type: Journal Article
Publication date: 2023-05-05
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
Current approaches to the reductive amination are often nonselective, require complicated catalysts, or are not atom-economical. The application of syngas as a mild and selective reducing agent to aminate carbonyl compounds unstable under hygrogenation conditions with functional groups, which furnished a broad substrate scope, is demonstrated herein. Amino acid precursor and furfurylamine derivative were prepared indicating the high selectivity of the protocol. Several products with antifungal activity higher than triadimefon were synthesized.
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Total citations:
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Citations from 2025:
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Podyacheva E. et al. Syngas as a synergistic reducing agent for the selective reductive amination – a mild route to bioactive amines // New Journal of Chemistry. 2023. Vol. 47. No. 22. pp. 10514-10518.
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Podyacheva E., Balalaeva A. I., Afanasyev O. I., Runikhina S. A., Chusova O., Kozlov A. S., Liao S., Chusov D. Syngas as a synergistic reducing agent for the selective reductive amination – a mild route to bioactive amines // New Journal of Chemistry. 2023. Vol. 47. No. 22. pp. 10514-10518.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d3nj01258a
UR - https://xlink.rsc.org/?DOI=D3NJ01258A
TI - Syngas as a synergistic reducing agent for the selective reductive amination – a mild route to bioactive amines
T2 - New Journal of Chemistry
AU - Podyacheva, Evgeniya
AU - Balalaeva, Alexandra I
AU - Afanasyev, Oleg I
AU - Runikhina, Sofiya A
AU - Chusova, Olga
AU - Kozlov, Andrey S
AU - Liao, Saihu
AU - Chusov, Denis
PY - 2023
DA - 2023/05/05
PB - Royal Society of Chemistry (RSC)
SP - 10514-10518
IS - 22
VL - 47
SN - 1144-0546
SN - 1369-9261
ER -
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BibTex (up to 50 authors)
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@article{2023_Podyacheva,
author = {Evgeniya Podyacheva and Alexandra I Balalaeva and Oleg I Afanasyev and Sofiya A Runikhina and Olga Chusova and Andrey S Kozlov and Saihu Liao and Denis Chusov},
title = {Syngas as a synergistic reducing agent for the selective reductive amination – a mild route to bioactive amines},
journal = {New Journal of Chemistry},
year = {2023},
volume = {47},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=D3NJ01258A},
number = {22},
pages = {10514--10518},
doi = {10.1039/d3nj01258a}
}
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MLA
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Podyacheva, Evgeniya, et al. “Syngas as a synergistic reducing agent for the selective reductive amination – a mild route to bioactive amines.” New Journal of Chemistry, vol. 47, no. 22, May. 2023, pp. 10514-10518. https://xlink.rsc.org/?DOI=D3NJ01258A.