Microphase separation transition for polyelectrolyte gels in poor solvents
Publication type: Journal Article
Publication date: 2003-08-05
Atomic and Molecular Physics, and Optics
Physics and Astronomy (miscellaneous)
General Engineering
Abstract
The microphase separation transition in the weakly charged polyelectrolyte gels immersed in poor solvent and undergoing collapse transition is studied in the weak crystallization approximation. The chain connectivity in the gel is taken into account ma introducing "polar- ization" term first proposed by de Gennes. It is shown that in this case the gel can undergo multistage jump-like collapse where the intermediate states can have regular microstructures of different symmetry,. The availability of numerous metastable states in the collapse region may lead to the pronounced hysteresis effects. These results are compared with some of the recent experimental findings.
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12
Total citations:
12
Citations from 2024:
1
(8%)
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GOST
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Zeldovich K. B. et al. Microphase separation transition for polyelectrolyte gels in poor solvents // Journal de Physique II. 2003. Vol. 7. No. 4. pp. 627-635.
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Zeldovich K. B., Dormidontova E., Khokhlov A. R., Vilgis T. A. Microphase separation transition for polyelectrolyte gels in poor solvents // Journal de Physique II. 2003. Vol. 7. No. 4. pp. 627-635.
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RIS
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TY - JOUR
DO - 10.1051/jp2:1997147
UR - https://doi.org/10.1051/jp2:1997147
TI - Microphase separation transition for polyelectrolyte gels in poor solvents
T2 - Journal de Physique II
AU - Zeldovich, Konstantin B.
AU - Dormidontova, E.E.
AU - Khokhlov, Alexei R.
AU - Vilgis, Thomas A.
PY - 2003
DA - 2003/08/05
PB - EDP Sciences
SP - 627-635
IS - 4
VL - 7
SN - 1155-4312
SN - 1286-4870
ER -
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BibTex (up to 50 authors)
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@article{2003_Zeldovich,
author = {Konstantin B. Zeldovich and E.E. Dormidontova and Alexei R. Khokhlov and Thomas A. Vilgis},
title = {Microphase separation transition for polyelectrolyte gels in poor solvents},
journal = {Journal de Physique II},
year = {2003},
volume = {7},
publisher = {EDP Sciences},
month = {aug},
url = {https://doi.org/10.1051/jp2:1997147},
number = {4},
pages = {627--635},
doi = {10.1051/jp2:1997147}
}
Cite this
MLA
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Zeldovich, Konstantin B., et al. “Microphase separation transition for polyelectrolyte gels in poor solvents.” Journal de Physique II, vol. 7, no. 4, Aug. 2003, pp. 627-635. https://doi.org/10.1051/jp2:1997147.
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